Solar-driven reduction of CO into renewable carbon forms is considered as an alternative approach to address global warming and the energy crisis but suffers from low efficiency of the photocatalysts. Herein, a direct Z-Scheme SnS /sulfur-bridged covalent triazine frameworks (S-CTFs) photocatalyst (denoted as SnS /S-CTFs) was developed, which could efficiently adsorb CO owing to the CO -philic feature of S-CTFs and promote separation of photoinduced electron-hole pairs. Under visible-light irradiation, SnS /S-CTFs exhibited excellent performance for CO photoreduction, yielding CO and CH with evolution rates of 123.6 and 43.4 μmol g h , respectively, much better than the most catalysts reported to date. This inorganic/organic hybrid with direct Z-Scheme structure for visible-light-driven CO photoreduction provides new insights for designing photocatalysts with high efficiency for solar-to-fuel conversion.
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