Plasmon-driven surface functionalization of nanoparticles is receiving increasing attention as it allows locally tailored chemical reactivity to be generated on the nanoparticle surface. The extension to surface multi-functionalization still represents a major breakthrough in chemistry. We address this issue by triggering regiospecific surface double-functionalization under plasmon excitation, using diazonium salts as surface functionalization agents.
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Facile preparation of bifunctional monolayers through diazonium grafting and "click" postfunctionalization: A first step towards efficient aptasensing interfaces.
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Department of Inorganic Chemistry, Physical Chemistry and Electrochemistry, National University of Science and Technology Politehnica Bucharest, 1-7 Gheorghe Polizu St., 011061 Bucharest, Romania. Electronic address:
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