This article reports the isolation and characterization of microcrystalline cellulose from date seeds of the date palm tree. The raw ground date seeds (RG-DS) are composed of cellulose matrix wrapped by lignin and hemicellulose as amorphous components. Cellulose was isolated from RG-DS through the following sequence: dewaxing, delignification/(bleaching) and acid hydrolysis. FTIR and Raman analysis for the bleached date seeds (B-DS) revealed the successful removal of the amorphous components from the polymer matrix. The X-ray diffractogram of the obtained (B-DS) exhibited the characteristic peaks of native cellulose (type I), with a crystallinity index (CrI = 62%). An additional acid hydrolysis step was used to convert native cellulose into microcrystalline cellulose (MCC-DS) with higher crystallinity (CrI = 70%). SEM analysis showed that the obtained microcrystals exhibit agglomerated and irregular elongated or semi-spherical shaped morphology. TEM analysis confirmed the semicrystalline nature of the MCC-DS. Thermal analysis showed enhanced thermal stability of MCC-DS. The current study shows the feasibility of using date seeds as a low-price source for obtaining MCC which is envisaged for applications in pharmaceutical and food industries as well as for preparing bionanocomposites with enhanced thermal properties.
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| http://dx.doi.org/10.1016/j.ijbiomac.2020.03.255 | DOI Listing |
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