We numerically investigate stress relaxation in soft athermal disks to reveal critical slowing down when the system approaches the jamming point. The exponents describing the divergence of the relaxation time differ dramatically depending on whether the transition is approached from the jammed or unjammed phase. This contrasts sharply with conventional dynamic critical scaling scenarios, where a single exponent characterizes both sides. We explain this surprising difference in terms of the vibrational density of states, which is a key ingredient of linear viscoelastic theory. The vibrational density of states exhibits an extra slow mode that emerges below jamming, which we utilize to demonstrate the anomalous exponent below jamming.
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http://dx.doi.org/10.1103/PhysRevLett.124.118001 | DOI Listing |
Polymers (Basel)
December 2024
C & S Partner, Hanam Technovalley U1 Center, Hanam-si 12982, Republic of Korea.
A fully bio-based polyester polyol based on isosorbide (ISB) and dimer fatty acid (DA) was synthesized through esterification. An ISB-based polyester polyol (DIS) was developed to synthesize a bio-based polyurethane elastomer (PUE) with enhanced mechanical and self-healing properties. The rigid bicyclic structure of ISB improved tensile properties, while the urethane bonds formed between the hydroxyl groups in ISB and isocyanate exhibited reversible characteristics at elevated temperatures, significantly enhancing the self-healing performance of DIS-based PUE compared to the control PUE (self-healing efficiency: 98% for DIS-based PUE vs.
View Article and Find Full Text PDFPolymers (Basel)
December 2024
Department of Materials Engineering, Taiyuan Institute of Technology, Taiyuan 030008, China.
Self-healing optically transparent polyimides have potential applications in optoelectronic device fabrication. In this study, for the first time, we successfully prepared a novel self-healing polyimide film containing reversible disulfide bonds through chemical imidization by introducing cystamine as a self-healing functional monomer into the molecular structure of conventional polyimides. The incorporation of cystamine enabled the films to maintain high transmittance (>87%) and tensile strength (>99 MPa).
View Article and Find Full Text PDFNutrients
December 2024
Institute for Health and Sport, Victoria University, Melbourne, VIC 3030, Australia.
Background: Obesity is a risk factor for developing cardiovascular diseases (CVDs) by impairing normal vascular function. Natural products are gaining momentum in the clinical setting due to their high efficacy and low toxicity. extract (CFE) has been shown to control appetite and promote weight loss; however, its effect on vascular function remains poorly understood.
View Article and Find Full Text PDFMaterials (Basel)
December 2024
Applied Materials Science, Uppsala University, SE-751 03 Uppsala, Sweden.
In additive manufacturing, the presence of residual stresses in produced parts is a well-recognized phenomenon. These residual stresses not only elevate the risk of crack formation but also impose limitations on in-service performance. Moreover, it can distort printed parts if released, or in the worst case even cause a build to fail due to collision with the powder scraper.
View Article and Find Full Text PDFInt J Mol Sci
December 2024
Department III Functional Sciences-Pathophysiology, Faculty of Medicine, "Victor Babeș" University of Medicine and Pharmacy of Timișoara, E. Murgu Sq., No. 2, 300041 Timisoara, Romania.
Black chokeberry (
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