The sucessful grafting of highly polar polymer chains both on the surface and in the subsurface of PDMS via subsurface initiated ATRP for the improved antibiofouling performance is enabled by the diffusion of organic solvents (in a water-based binary solvent) which act as not only a "carrier" for hydrophilic monomers but also a "sweller" for the PDMS substrate.
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http://dx.doi.org/10.1039/d0cc00768d | DOI Listing |
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January 2025
School of Materials and Physics & Center of Mineral Resource Waste Recycling, China University of Mining and Technology, Xuzhou, Jiangsu, 221116, China.
Designing spent graphite anodes from lithium-ion batteries (LIBs) for applications beyond regenerated batteries offers significant potential for promoting the recycling of spent LIBs. The battery-grade graphite, characterized by a highly graphitized structure, demonstrates excellent conductive loss capabilities, making it suitable for microwave absorption. During the Li-ion intercalation and deintercalation processes in battery operation, the surface layer of spent graphite (SG) becomes activated, forming oxygen-rich functional groups that enhance the polarization loss mechanism.
View Article and Find Full Text PDFJ Am Chem Soc
January 2025
School of Rare Earths, University of Science and Technology of China, Hefei 230026, China.
Achieving ultrahigh permeance and superoleophobicity is crucial for membrane application. Here, we demonstrated that a poly(ionic liquid)/PES hydrogel membrane can achieve dual goals. The high polarity of the ionic liquids induces the water molecules on the membrane surface to be arranged more ordered, as verified by molecular dynamics (MD) simulation and advanced femtosecond sum frequency generation (SFG) vibrational spectroscopy.
View Article and Find Full Text PDFRSC Adv
January 2025
Norwegian Tribology Center, Department of Mechanical and Industrial Engineering, Norwegian University of Science and Technology (NTNU) Trondheim Norway
The focus on energy efficiency to move towards a more sustainable use of resources has intensified efforts to minimize friction and wear in mechanical systems, which account for 23% of the world's energy consumption. In this study, polyoxometalate ionic liquids (POM-ILs) are introduced as environmentally acceptable lubricant additives, for their potential friction-reducing and anti-wear (AW) properties. These compounds, characterized by their complex structures and tunable properties, have been investigated for their tribological performance across base fluids of varying polarities.
View Article and Find Full Text PDFHum Mol Genet
January 2025
Section on Translational Neuroscience, Eunice Kennedy Shriver National Institute of Child Health and Human Development, National Institutes of Health, 9000 Rockville Pike, Bethesda, MD 20892, USA.
The choroid plexuses (CP) are highly vascularized structures that project into the ventricles of the vertebrate brain. The polarized epithelia of the CP produce cerebrospinal fluid by transporting water and ions into the ventricles from the blood and normally secrete a large number of proteins. We assessed the feasibility of selective CP transduction with recombinant adeno-associated virus (rAAV) gene therapy vectors for treatment of lysosomal storage disease (LSD), a broad category of neurometabolic illness associated with significant burdens to affected patients and their families.
View Article and Find Full Text PDFMetasurfaces offer a powerful tool to realize label-free and highly sensitive Raman spectroscopy. Embedding metasurfaces into microfluidic channels is promising to establish a new characterizing platform for microfluids. In this Letter, we present a highly stable method for improving the Raman scattering intensity of biological microfluids by using a microfluidic chip embedded with a plasmonic metasurface.
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