Fluorescent conjugated microporous polymers containing pyrazine moieties for adsorbing and fluorescent sensing of iodine.

Two kinds of fluorescent conjugated microporous polymers containing pyrazine moieties were prepared by the polymerization reaction of 2,5-di-triphenylamine-yl-pyrazine (DTPAPz) and N,N,N',N'-tetrapheny-2,5-(diazyl) pyrazine (TDPz) with 2,4,6-trichloro-1,3,5-triazine (TCT) through Friedel-Crafts reaction using the methanesulfonic acid as a catalysts. Both CMPs have high thermal stability and decomposition temperature reaches above 596 and 248 °C under nitrogen atmosphere, respectively. By right of porous morphology and electron-donating nitrogen, as well as electron-rich π-conjugated structures, the adsorption performance for iodine vapor on the CMPs is very excellent, which can reach 441% and 312%. In addition, fluorescence studies showed that the two CMPs exhibited high fluorescence sensitivity to electron-deficient iodine, o-nitrophenol (o-NP), and picric acid (PA) via fluorescence quenching.