We study the size-dependent optical properties of periodic arrays of semiconducting nanolines in the near-infrared to near-ultraviolet spectral range, where the absorption of the semiconductor increases. Using band structure calculations, we demonstrate that specific dimensions allow the slow down of the light, resulting in an enhanced absorption as compared to bulk material once the extinction coefficient of the semiconductor becomes comparable to its refractive index. Further, the refractive properties of the arrays can be tailored beyond the values of the constituting materials when the extinction coefficient of the semiconductor exceeds its refractive index. To confirm our theoretical findings, we propose a simple semi-analytical model for the light interactions with such structures and validate it with experimental reflectance spectra collected on arrays for the next-generation transistors.
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http://dx.doi.org/10.1364/OE.386964 | DOI Listing |
Chem Asian J
December 2024
Department of Chemistry and Biochemistry, The University of Oklahoma, 101 Stephenson Parkway, Norman, OK, 73019.
Proton-coupled electron transfer (PCET) reactions are fundamental to energy storage and conversion processes. By coupling electrons with protons, the net charge neutrality is retained, preventing electrode decomposition due to charge imbalance. PCET reactions with equimolar amounts of protons and electrons can be considered as a net H-atom transfer (HAT) reaction.
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December 2024
School of Physical Sciences and Nanotechnology, Yachay Tech University, Urcuquí 100119, Ecuador.
Samarium-doped nanohydroxyapatite is a biomaterial with nerve regeneration activity and bioimaging. In this work, Sm/HAp; (Ca Sm (PO)(OH)) (0 ≤ ≤ 1) was synthesized using the hydrothermal method and thermally treated from 200 to 800 °C. The samples were characterized by transmission electron microscopy, energy-dispersive X-ray spectroscopy, Fourier transform infrared spectroscopy, X-ray diffraction, Raman spectroscopy, and luminescence spectroscopy.
View Article and Find Full Text PDFNanomaterials (Basel)
December 2024
Laser Institute for Research and Applications LIRA, Beni-Suef University, Beni-Suef 62511, Egypt.
In this report, the nonlinear optical (NLO) properties of titanium dioxide nanoparticles (TiO NPs) have been explored experimentally using femtosecond laser light along with the Z-scan approach. The synthesis of TiO NPs was carried out in distilled water through nanosecond second harmonic Nd:YAG laser ablation. Characterization of the TiO NPs colloids was conducted using UV-visible absorption spectroscopy, transmission electron microscopy (TEM), inductively coupled plasma (ICP), and energy-dispersive X-ray spectroscopy (EDX).
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December 2024
Department of Chemistry, University of California Berkeley, Berkeley, California 94720, United States.
The development of a colloidal synthesis procedure to produce nanomaterials with high shape and size purity is often a time-consuming, iterative process. This is often due to quantitative uncertainties in the required reaction conditions and the time, resources, and expertise intensive characterization methods required for quantitative determination of nanomaterial size and shape. Absorption spectroscopy is often the easiest method for colloidal nanomaterial characterization.
View Article and Find Full Text PDFNanomaterials (Basel)
November 2024
Hangzhou Institute for Advanced Study, University of Chinese Academy of Sciences, Hangzhou 310024, China.
Semiconductor nanoparticles of sizes smaller than exciton Bohr diameters undergo quantum confinement and are called quantum dots (QDs), which exhibit size-dependent physicochemical properties [...
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