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Synthesis of CH-linked α-galactosylceramide and its glucose analogues through glycosyl radical-mediated direct C-glycosylation. | LitMetric
We describe a new synthetic approach for C-linked glycolipid analogues, in which the cleavable O-glycosidic linkage is replaced by a carbon unit. Direct C-glycosylation of a conformationally constrained and stable C1-sp hybridized xanthate carbohydrate with carefully designed sphingosine units afforded the CH-linked analogue of antitumor-active KRN7000 and its glucose congener.
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