This work unveils the roles played by potato starch (ST) in the immobilization, photochemical reduction, and gas sensitivity of graphene oxide (GO) films. The ST/GO films are assembled layer by layer (LbL) onto quartz substrates by establishing mutual hydrogen bonds that drive a stepwise film growth, with equal amounts of materials being adsorbed in each deposition cycle. Afterward, the films are photochemically reduced with UV irradiation (254 nm), following a first-order kinetics that proceeds much faster when GO is assembled along with ST instead of a nonoxygenated polyelectrolyte, namely, poly(diallyl dimethylammonium) hydrochloride (PDAC). Finally, the gas-sensing performance of ST/reduced graphene oxide (RGO) and PDAC/RGO sensors fabricated via LbL atop of gold interdigitated microelectrodes is evaluated at different relative humidity levels and in different concentrations of ammonia, ethanol, and acetone. In comparison to the PDAC/RGO sensor, the ones containing ST are much more sensitive, especially when operating in a high-relative-humidity environment. An array comprising these chemical sensors provides unique electrical fingerprints for each of the investigated analytes and is capable of discriminating and quantifying them in a wide range of concentrations, from 10 to 1000 ppm.
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http://dx.doi.org/10.1021/acsomega.9b03892 | DOI Listing |
Pharmaceutics
December 2024
Department of General Surgery, The Fifth People's Hospital of Shanghai, Fudan University, Shanghai 200240, China.
Background/objectives: Colorectal cancer (CRC) is characterized by a high rate of both incidence and mortality, and its treatment outcomes are often affected by recurrence and drug resistance. Ferroptosis, an iron-dependent programmed cell death mechanism triggered by lipid peroxidation, has recently gained attention as a potential therapeutic target. Graphene oxide (GO), known for its oxygen-containing functional groups, biocompatibility, and potential for functionalization, holds promise in cancer treatment.
View Article and Find Full Text PDFPlants (Basel)
December 2024
Jiangsu Key Laboratory of Atmospheric Environment Monitoring and Pollution Control, Collaborative Innovation Center of Atmospheric Environment and Equipment Technology, School of Environmental Science and Engineering, Nanjing University of Information Science and Technology, Nanjing 210044, China.
Global pollution caused by micro/nanoplastics (M/NPs) is threatening agro-ecosystems, compromising food security and human health. Also, the increasing use of graphene-family nanomaterials (GFNs) in agricultural products has led to their widespread presence in agricultural systems. However, there is a large gap in the literature on the combined effects of MNPs and GFNs on agricultural plants.
View Article and Find Full Text PDFMaterials (Basel)
December 2024
Institute of Optoelectronics, Military University of Technology, gen. S. Kaliskiego 2, 00-908 Warsaw, Poland.
In order to improve the performance of cement mortar (Portland cement), it was enriched with triclosan, hypochlorous acid, silver nanoparticles and graphene oxide. Cement mortar is used, among other things, to fill the gaps between the tiles of building porcelain stoneware. A number of structural, mechanical and biological tests were carried out.
View Article and Find Full Text PDFMaterials (Basel)
December 2024
Cracow University of Technology, Faculty of Chemical Engineering and Technology, Warszawska 24, 31-155 Krakow, Poland.
Direct lithium extraction from unconventional resources requires the development of effective adsorbents. Crown ether-containing materials have been reported as promising structures in terms of lithium selectivity, but data on adsorption in real, highly saline brines are scarce. Crown ether-grafted graphene oxides were synthesized using 2-hydroxymethyl-12-crown-4, hydroxy-dibenzo-14-crown-4 and epichlorohydrin as a source of anchoring groups.
View Article and Find Full Text PDFMaterials (Basel)
December 2024
Department of Chemical Engineering, Faculty of Chemistry, Campus of Espinardo, University of Murcia, 30100 Murcia, Spain.
Nowadays, there is a growing interest in membrane modification processes to improve their characteristics and the effectiveness of their treatments and reduce the possible fouling. In this sense, in this work, a modification of an ultrafiltration membrane with three different materials has been carried out: reduced graphene oxide (rGO), chitosan and MgCl. For both the native and the modified membranes, a study has been carried out to remove the emerging contaminant sulfamethoxazole (SMX).
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