In/H-Beta catalyst was prepared by optimizing the support, concentration of ion exchange liquid and calcination temperature to investigate the effects of synthesis conditions on catalytic activity of selective catalytic reduction of NO with CH. The results showed that the In/H-Beta catalyst exhibited the superior activity when concentration of exchange liquid was 0.033 M and calcination temperature was 500 °C, the NO removal ratio could reach 97.6%. In addition, reaction conditions could affect the catalytic performance. When O concentration was 10%, CH:NO ratio was no less than one, space velocity was lower than 23600 h and NO initial concentration was no more than 700 ppm, In/H-Beta could exhibit superior catalytic activity. Moreover, the catalytic performances of In/H-Beta catalysts were discussed after enduring HO or/and SO. This novel strategy could open the door for selective catalytic reduction of NO with CH.
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http://dx.doi.org/10.1016/j.chemosphere.2020.126458 | DOI Listing |
Analyst
January 2025
School of Chemistry, Institute of Science, Suranaree University of Technology, 111 University Avenue, Muang District, Nakhon Ratchasima 30000, Thailand.
Nicotinamide adenine dinucleotide is a crucial coenzyme in cellular metabolism and is implicated in various diseases. This work introduces an electrochemical bioanalytical method utilizing solution-phase formate dehydrogenase (CbFDH) for detecting its oxidized form (NAD) in human blood plasma samples. The detection mechanism involves the catalytic conversion of NAD to NADH, facilitated by CbFDH in the presence of formate.
View Article and Find Full Text PDFLangmuir
January 2025
Prof. Rashidi Laboratory of Organometallic Chemistry & Material Chemistry, Department of Chemistry, College of Science, Shiraz University, Shiraz, 7194684795, Iran.
In this study, a Pd nanoparticles@hydrogen-bonded organic framework (Pd NPs@HOF) thin film was fabricated at the toluene-water interface. The HOF was formed through the interaction of trimesic acid (TMA) and melamine (Mel) in the water phase, while Pd(0) was produced from the reduction of [PdCl(cod)] in the organic phase. The as-synthesized Pd NPs@HOF thin film was demonstrated to be an effective catalyst for the selective reduction of -nitrophenol and -nitrophenol to -aminophenol and -aminophenol.
View Article and Find Full Text PDFChem Asian J
January 2025
Rheinisch-Westfalische Technische Hochschule Aachen, Organic Chemistry, Landoltw, 52074, Aachen, GERMANY.
Highly reactive oxygen and nitrogen species (ROS/RNS) play crucial roles in various pathological conditions. Among them, hypochlorous ion (OCl⁻), a potent ROS, is associated in numerous oxidative stress-related disorders. Elevated levels of OCl⁻ are thus recognized as a biomarker for diagnosing inflammatory conditions.
View Article and Find Full Text PDFACS Nano
January 2025
Creative Research Initiative Center for Nanospace-confined Chemical Reactions (NCCR), Pohang University of Science and Technology (POSTECH), Pohang 37673, Korea.
Unlike homogeneous metal complexes, achieving absolute control over reaction selectivity in heterogeneous catalysts remains a formidable challenge due to the unguided molecular adsorption/desorption on metal-surface sites. Conventional organic surface modifiers or ligands and rigid inorganic and metal-organic porous shells are not fully effective. Here, we introduce the concept of "ligand-porous shell cooperativity" to desirably reaction selectivity in heterogeneous catalysis.
View Article and Find Full Text PDFOrg Biomol Chem
January 2025
Department of Chemistry, Jadavpur University, Kolkata 700032, India.
2-Arylbenzoxazinone undergoes direct -C-H thiolation by using diaryl disulfide in the presence of a Ru(II)-phosphine catalytic system and an Ag additive. The protocol has been generalized with benzoxazinone substrates having different substituents and a series of disulfides. -Selenylation has also been performed successfully using diphenyl diselenide under similar catalytic conditions.
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