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Resolving Enhanced Mn Luminescence near the Surface of CsPbCl with Time-Resolved Cathodoluminescence Imaging. | LitMetric

AI Article Synopsis

Article Abstract

Mn doping of lead halide perovskites has garnered recent interest because it produces stable orange luminescence in tandem with perovskite emission. Here, we observe enhanced Mn luminescence at the edges of Mn-doped CsPbCl perovskite microplates and suggest an explanation for its origin using the high spatiotemporal resolution of time-resolved cathodoluminescence (TRCL) imaging. We reveal two luminescent decay components that we attribute to two different Mn populations. While each component appears to be present both near the surface and in the bulk, the origin of the intensity variation stems from a higher proportion of the longer lifetime component near the perovskite surface. We suggest that this higher emission is caused by an increased probability of electron-hole recombination on Mn near the perovskite surface due to an increased trap concentration there. This observation suggests that such surface features have yet untapped potential to enhance emissive properties via control of surface-to-volume ratio.

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Source
http://dx.doi.org/10.1021/acs.jpclett.0c00574DOI Listing

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