AI Article Synopsis
- The study focuses on a method called vapour-phase surface-initiated cationic polymerisation, specifically using ethylvinylether on single-crystals of a certain rhodium complex.
- This new approach effectively makes materials that are usually sensitive to air more resistant to it, improving their usability.
- Additionally, the technique allows for continued chemical reactions between single crystals, particularly at the metal sites of the crystal structure.
Article Abstract
Vapour-phase surface-initiated cationic polymerisation of ethylvinylether occurs at single-crystals of the σ-alkane complex [Rh(CyPCHCHPCy)(NBA)][BAr]. This new surface interface makes these normally very air sensitive materials tolerant to air, while also allowing for onward single-crystal to single-crystal reactivity at metal sites within the lattice.
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| http://dx.doi.org/10.1039/d0cc01140a | DOI Listing |
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