Sea spray aerosol formation: Results on the role of different parameters and organic concentrations from bubble bursting experiments.

Submicron sea spray aerosol (SSA) particles play an essential role in atmospheric chemical processes and the Earth's radiative balance. In this study, different combinations of NaCl, MgSO, malonic acid (MA), d-fructose and sodium malonate were used to explore the effect of MA on submicron SSA generation. SSA particles were produced at room temperature by bubble bursting from an adjustable home-built SSA generator with sintered glass filters. We found that MA could promote the generation of SSA particles and make the geometric mean diameter (GMD) to decrease for MA concentrations ranging between 8 and 32 mM and then, to increase for MA concentrations in the range of 64-160 mM. d-fructose could improve the generation of SSA with increasing GMD. Interestingly, sodium malonate could significantly enhance the production of SSA, with the change of morphology. Besides, different parameters including flow rate, underwater depth, pore size and size span of sintered glass filter and salinity of water were tested to obtain the characterization of our self-made adjustable SSA generator. Three modes could be found among different SSA generation methods, and they exhibited an obvious accumulation mode around 100 nm. The SSA generation under different conditions was compared with oceanic measurements from the literature, which showed that the sintered glass filter has advantages in generating submicron SSA from film drops.