The magnesium uranyl tricarbonate octadecahydrate mineral, bayleyite: Periodic DFT study of its crystal structure, hydrogen bonding, mechanical properties and infrared spectrum.

Bayleyite is a highly hydrated uranyl tricarbonate mineral containing eighteen water molecules per formula unit. Due to this large water content, the correct description of its crystal structure is a great challenge for the first principles solid state methodology. In this work, the crystal structure, hydrogen bonding, mechanical properties and infrared spectrum of bayleyite, Mg[UO(CO)] · 18 HO, have been investigated by means of Periodic Density Functional Theory methods using plane wave basis sets and pseudopotentials. The computed unit-cell parameters, interatomic distances, hydrogen bonding network geometry and the X-ray powder diffraction pattern of bayleyite reproduce successfully the experimental data, thus confirming the crystal structure determined from X-ray diffraction data. From the energy-optimized structure, the elastic properties and infrared spectrum have been determined using theoretical methods. The calculated elastic properties include the bulk modulus and its pressure derivatives, the Young and shear moduli, the Poisson ratio and the ductility, hardness and anisotropy indices. Bayleyite is shown to be a very isotropic ductile mineral possessing a bulk modulus of B ~28 GPa. The infrared spectrum of bayleyite is obtained experimentally from a natural mineral sample from the Jáchymov ore district, Czech Republic, and determined employing density functional perturbation theory. Since both spectra show a high degree of consistence, the bands in the observed spectrum are assigned using the theoretical methodology. The atomic vibrational motions localized in the uranyl tricarbonate units are described in detail, using appropriate normal coordinate analyses based on accurate vibrational computations, since the vibrational normal modes have not been hitherto studied for any uranyl tricarbonate mineral.