Comparative assessment of the degradation of 2-methylisoborneol and geosmin in freshwater using advanced oxidation processes.

Traditional methodologies of conventional drinking water treatment are unable to remove some chemical compounds, such as those that cause odor and taste in drinking water. The present work aims to evaluate the efficiency of advanced oxidations processes, using UV radiation, O and O + UV in the degradation of geosmin (GSM) and 2-methylisoborneol (2-MIB) in synthetic samples. The efficiency of the processes was monitored by Gas Chromatography coupled with Mass Spectrometry using solid phase microextration technique. Experiments were carried out for 45 min with samplings every 15 min. The degradation results showed that UV radiation alone was not efficient for the degradation of both compounds. The fasted decay was observed by the combined use of O and UV with an ozone concentration of 15.84 mg L. Under these conditions, the final concentration of GSM was below the limit of quantification, so that approximately 99% of the initial concentration was degraded, while 2-MIB was degraded by 95%. With the same O concentration without the use of UV radiation, 63% and 65.7% of MIB and GSM, respectively, were removed. Higher efficiency of the treatment was observed with a higher O concentration which allows a shorter reaction time.