A two-step process, which involved ferric leaching with biologically generated solution and subsequent biooxidation with the microbial community, has been previously proposed for the processing of low-grade zinc sulfide concentrates. In this study, we carried out the process of complete biological oxidation of the product of ferric leaching of the zinc concentrate, which contained 9% of sphalerite, 5% of chalcopyrite, and 29.7% of elemental sulfur. After 21 days of biooxidation at 40°C, sphalerite and chalcopyrite oxidation reached 99 and 69%, respectively, while the level of elemental sulfur oxidation was 97%. The biooxidation residue could be considered a waste product that is inert under aerobic conditions. The results of this study showed that zinc sulfide concentrate processing using a two-step treatment is efficient and promising. The microbial community, which developed during biooxidation, was dominated by , and sp. At the same time, and played crucial roles in the oxidation of sulfide minerals and elemental sulfur, respectively. The addition of to during biooxidation of the ferric leach product proved to inhibit elemental sulfur oxidation.
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http://dx.doi.org/10.3390/microorganisms8030386 | DOI Listing |
Graphene 2D Mater
June 2024
NanoSafe, Inc., Blacksburg, VA 24060, USA.
Five commercially available cut-resistant gloves were sourced from four different worldwide manufacturers which were advertised to contain graphene. A method was developed to assess the fibers composing each glove, including dissolution of the constituent fibers using sulfuric acid or liquid paraffin at elevated temperature, to extract and analyze particle additives. Scanning electron microscopy with energy-dispersive X-ray spectroscopy was applied to fibers and extracted particles for morphological and elemental analysis; Raman spectroscopy was applied to discern the composition of carbonaceous materials for the ultimate purpose of identifying any graphenic additives.
View Article and Find Full Text PDFChem Mater
January 2025
Graduate School of Biomedical Science and Engineering, Koç University, Istanbul 34450, Türkiye.
AgBiS nanocrystals (NCs), composed of nontoxic, earth-abundant materials and exhibiting an exceptionally high absorption coefficient from visible to near-infrared (>10 cm), hold promise for photovoltaics but have lack of photoluminescence (PL) due to intrinsic nonradiative recombination and challenging shell growth. In this study, we reported a facile wet-chemical approach for the epitaxial growth of ZnS shell on AgBiS NCs, which triggered the observation of PL emission in the near-infrared (764 nm). Since high quality of the core is critical for epitaxial shell growth, we first obtained rock-salt structured AgBiS NCs with high crystallinity, nearly spherical shape and monodisperse size distribution (<6%) via a dual-ligand approach reacting Ag-Bi oleate with elemental sulfur in oleylamine.
View Article and Find Full Text PDFInorg Chem
January 2025
State Key Laboratory of Clean and Efficient Coal Utilization, Taiyuan University of Technology, Taiyuan 030024, China.
The low sulfur selectivity of Fe-based HS-selective catalytic oxidation catalysts is still a problem, especially at a high O content. This is alleviated here through anchoring FeO nanoclusters on UiO-66 via the formation of Fe-O-Zr bonds. The introduced FeO species exist in the form of Fe and Fe.
View Article and Find Full Text PDFSci Total Environ
January 2025
Institute of Microbiology of the National Academy of Sciences of Belarus, Acad. Kuprevich str., 2, 220084 Minsk, Belarus.
There is an urgent need to develop effective and sustainable methods to decrease sulfonamide (SA) contamination of soil. Herein, a non-homogeneous system of zero-valent metal-biochar-based composites was proposed and tested for persulfate (PS) activation. This system employed zero-valent iron (Fe) as an electron donor to catalyze the cleavage of the OO bond in PS, thereby generating reactive oxygen species (ROS) that degrade SAs.
View Article and Find Full Text PDFJ Hazard Mater
January 2025
State Key Lab of Geohazard prevention & Geoenvironment protection, College of Materials and Chemistry & Chemical Engineering, Chengdu University of Technology, Chengdu 610059, China. Electronic address:
Sulfur nanoparticles (SNPs) and their composites are promising for heavy metal adsorption, yet current SNPs often lack surface S, leading to low affinity toward heavy metal and ease of aggregation. Here, we report a simple light-driven method for facile prepare SNPs with surfaces enriched with S and in-situ load them onto graphene oxide (GO) to fabricate GO-S composites. Under illumination, the O generated by photosensitizer phloxine B was able to oxidize S into elemental SNPs.
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