Laboratory astrochemists have generated infrared (IR) data for nearly all common classes of organic compounds, but ethers in the solid phase continue to be neglected despite detections of ethers in the interstellar medium by radio astronomers and uncertainty in how extraterrestrial ethers are formed. To address this paucity of data, here we present new mid-IR spectra of amorphous and crystalline dimethyl ether, (CH)O, the simplest member of its class. Spectral positions are tabulated and compared to previous results, but more importantly we also report IR band strengths and absorption coefficients, which we have not found in the literature and on which quantitative IR studies depend. Optical constants of amorphous and crystalline dimethyl ether also have been calculated. Some applications are described.
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http://dx.doi.org/10.1016/j.saa.2020.118217 | DOI Listing |
Sci Rep
January 2025
Department of Graphic Arts and Photophysics, Faculty of Chemical Technology, University of Pardubice, Studentská 573, Pardubice, 532 10, Czech Republic.
Radio frequency magnetron co-sputtering method employing GeTe and Sc targets was exploited for the deposition of Sc doped GeTe thin films. Different characterization techniques (scanning electron microscopy with energy-dispersive X-ray analysis, X-ray diffraction, atomic force microscopy, sheet resistance temperature-dependent measurements, variable angle spectroscopic ellipsometry, and laser ablation time-of-flight mass spectrometry) were used to evaluate the properties of as-deposited (amorphous) and annealed (crystalline) Ge-Te-Sc thin films. Prepared amorphous thin films have GeTe, GeTeSc, GeTeSc, GeTeSc and GeTeSc chemical composition.
View Article and Find Full Text PDFNanotechnology
January 2025
MME, Wright State University, 3640 Colonel Glenn Hwy, Lake Campus, 7600 Lake Drive, Lake Campus, Fairborn, Ohio, 45435, UNITED STATES.
Surface induced crystallization/amorphization of a Germanium-antimony-tellurium (GST) nanolayer is investigated using the phase field model. A Ginzburg-Landau (GL) equation introduces an external surface layer (ESL) within which the surface energy and elastic properties are properly distributed. Next, the coupled GL and elasticity equations for the crystallization/amorphization are solved.
View Article and Find Full Text PDFNat Commun
January 2025
State Key Laboratory Breeding Base of Green Chemistry Synthesis Technology and College of Chemical Engineering, Center for Electron Microscopy, Institute for Frontier and Interdisciplinary Sciences, Zhejiang University of Technology, Hangzhou, Zhejiang, China.
Recent advances in direct electron detectors and low-dose imaging techniques have opened up captivating possibilities for real-space visualization of radiation-induced structural dynamics. This has significantly contributed to our understanding of electron-beam radiation damage in materials, serving as the foundation for modern electron microscopy. In light of these developments, the exploration of more precise and specific beam damage mechanisms, along with the development of associated descriptive models, has expanded the theoretical framework of radiation damage beyond classical mechanisms.
View Article and Find Full Text PDFNat Commun
January 2025
Department of Materials Science & International Institute of Intelligent Nanorobots and Nanosystems, State Key Laboratory of Surface Physics, Fudan University, Shanghai, 200438, People's Republic of China.
The recently emerged remote epitaxy technique, utilizing 2D materials (mostly graphene) as interlayers between the epilayer and the substrate, enables the exfoliation of crystalline nanomembranes from the substrate, expanding the range of potential device applications. However, remote epitaxy has been so far applied to a limited range of material systems, owing to the need of stringent growth conditions to avoid graphene damaging, and has therefore remained challenging for the synthesis of oxide nanomembranes. Here, we demonstrate the remote epitaxial growth of an oxide nanomembrane (vanadium dioxide, VO) with a sub-nanometer thick amorphous interlayer, which can withstand potential sputtering-induced damage and oxidation.
View Article and Find Full Text PDFInt J Pharm
December 2024
Sciences Center of Imperatriz, Federal University of Maranhão - UFMA, 65900-410, Imperatriz, MA, Brazil. Electronic address:
This study reports the synthesis and the experimental-theoretical characterization of a new coamorphous system consisting of ethionamide (ETH) and mandelic acid (MND) as a coformer. The solid dispersion was synthesized using the slow solvent evaporation method in an ethanolic medium. The structural, vibrational, and thermal properties of the system were characterized.
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