Visualization of the slide-ring effect: a study on movable cross-linking points using mechanochromism.

Chem Commun (Camb)

Department of Chemical Science and Engineering, Tokyo Institute of Technology, Meguro-ku, Oookayama 2-12-1 S1-6, Tokyo, Japan.

Published: March 2020

AI Article Synopsis

  • The study focuses on the 'slide-ring' effect in a special type of polymer network called rotaxane by adding color-changing molecules (mechanochromophores) at the cross-linking points.
  • Researchers compared the color changes (mechanochromisms) of polymers created through traditional static cross-linking versus rotaxane cross-linking to understand the differences in behavior.
  • This new approach not only shows visible color changes at a molecular level but also allows for precise measurements using electron paramagnetic resonance techniques.

Article Abstract

To evaluate the 'slide-ring' effect in a rotaxane cross-linked network, we incorporated mechanochromophores into static and rotaxane cross-linking points and compared the mechanochromisms exhibited by the obtained polymers. This novel strategy reveals a molecular-level phenomenon with visible color changes as well as enabling quantitative electron paramagnetic resonance measurements.

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Source
http://dx.doi.org/10.1039/c9cc09452kDOI Listing

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