A two-step approach of improving the thermoelectric properties of Poly(3,4-ethylenedioxythiophene)poly(4-styrenesulfonate) (PEDOT:PSS) via the addition of the ionic liquid, 1-Ethyl-3-methylimidazolium bis(trifluoromethylsulfonyl)imide (EMIM:TFSI) and subsequent reduction with NaBH is presented. The addition of 2.5 v/v% of EMIM:TFSI to PEDOT:PSS increases the electrical conductivity from 3 S·cm to 1439 S·cm at 40 °C. An additional post treatment using the reducing agent, NaBH, increases the Seebeck coefficient of the film from 11 µV·K to 30 µV·K at 40 °C. The combined treatment gives an overall improvement in power factor increase from 0.04 µW·m·K to 33 µW·m·K below 140 °C. Raman and XPS measurements show that the increase in PEDOT:PSS conductivity is due to PSS separation from PEDOT and a conformational change of the PEDOT chains from the benzoid to quinoid molecular orientation. The improved Seebeck coefficient is due to a reduction of charge carriers which is evidenced from the UV-VIS depicting the emergence of polarons.
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| http://dx.doi.org/10.3390/polym12030559 | DOI Listing |
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