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We investigated the growth and auto-oxidation of Pd deposited onto a AgOx single-layer on Ag(111) using scanning tunneling microscopy (STM) and X-ray photoelectron spectroscopy (XPS). Palladium initially grows as well-dispersed, single-layer clusters that adopt the same triangular shape and orientation of Agn units in the underlying AgOx layer. Bi-layer clusters preferentially form upon increasing the Pd coverage to ∼0.30 ML (monolayer) and continue to develop until aggregating and forming a nearly conformal Pd bi-layer at a coverage near 2 ML. Analysis of the STM images provides quantitative evidence of a transition from single to bi-layer Pd growth on the AgOx layer, and a continuation of bi-layer growth with increasing Pd coverage from ∼0.3 to 2 ML. XPS further demonstrates that the AgOx layer efficiently transfers oxygen to Pd at 300 K, and that the fraction of Pd that oxidizes is approximately equal to the local oxygen coverage in the AgOx layer for Pd coverages up to at least ∼0.7 ML. Our results show that oxygen in the initial AgOx layer mediates the growth and structural properties of Pd on the AgOx/Ag(111) surface, enabling the preparation of model PdAg surfaces with uniformly distributed single or bi-layer Pd clusters. Facile auto-oxidation of Pd by AgOx further suggests that oxygen transfer from Ag to Pd could play a role in promoting oxidation chemistry of adsorbed molecules on PdAg surfaces.
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http://dx.doi.org/10.1039/c9cp06973a | DOI Listing |
ACS Nano
January 2024
Key Laboratory for Micro-Nano Optoelectronic Devices of Ministry of Education, School of Physics and Electronics, Hunan University, Changsha 410082, China.
Two-dimensional (2D) semiconductors have generated considerable attention for high-performance electronics and optoelectronics. However, to date, it is still challenging to mechanically exfoliate large-area and continuous monolayers while retaining their intrinsic properties. Here, we report a simple dry exfoliation approach to produce large-scale and continuous 2D monolayers by using a Ag film as the peeling tape.
View Article and Find Full Text PDFNanoscale Res Lett
March 2021
DLR Institute of Networked Energy Systems, Urban and Residential Technologies, Carl-von-Ossietzky-Str. 15, 26129, Oldenburg, Germany.
Oxide/metal/oxide (OMO) layer stacks are used to replace transparent conductive oxides as front contact of thin-film solar cells. These multilayer structures not only reduce the overall thickness of the contact, but can be used for colouring of the cells utilizing interference effects. However, sheet resistance and parasitic absorption, both of which depend heavily on the metal layer, should be further reduced to reach higher efficiencies in the solar cells.
View Article and Find Full Text PDFACS Appl Mater Interfaces
September 2020
Key Laboratory of Functional Materials Physics and Chemistry of the Ministry of Education, Jilin Normal University, Changchun 130103, China.
In the past few years, the power conversion efficiencies (PCEs) of perovskite solar cells (PSCs) have increased from 3.81 to 25.2%, surpassing those of all almost all thin films solar cells.
View Article and Find Full Text PDFPhys Chem Chem Phys
March 2020
Department of Chemical Engineering, University of Florida, Gainesville, FL 32611, USA.
We investigated the growth and auto-oxidation of Pd deposited onto a AgOx single-layer on Ag(111) using scanning tunneling microscopy (STM) and X-ray photoelectron spectroscopy (XPS). Palladium initially grows as well-dispersed, single-layer clusters that adopt the same triangular shape and orientation of Agn units in the underlying AgOx layer. Bi-layer clusters preferentially form upon increasing the Pd coverage to ∼0.
View Article and Find Full Text PDFJ Nanosci Nanotechnol
November 2015
Unlabelled: We demonstrated a fabrication process using UV-Ozone treatment to obtain a qualified silver oxide (AgOx) film to be anode, and then spinning the poly(3,4-ethylenedioxythiophene) poly(styrenesulfonate) (
Pedot: PSS) layer on the Ag/AgOx anode to smooth the its surface, resulting to efficiency improvement of the organic photovoltaic (OPV). The basic OPV structure mainly contained with a high reflective Ag anode, a semitransparent Ag cathode and a planar heterojunction small molecular active layer. Surface morphologies, roughness, reflectivity and workfunction of Ag/AgOx anode with various UV-Ozone treatment times were investigated to affect the device performance.
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