A copper-catalyzed, directed C-H diarylamination of indoles, indolines, anilines, and -aryl-7-azaindoles has been established. Only copper salt as the catalyst and oxygen as the terminal oxidant are used to synthesize triarylamines using various diarylamines including carbazole and phenothiazine. Mechanistic interrogation reveals that copper plays a dual role.
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Electron transfer kinetics of a series of copper complexes with tripodal tetradentate guanidine quinolinyl ligands.
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Institute of Inorganic Chemistry, RWTH Aachen University, Landoltweg 1a, 52074 Aachen, Germany.
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School of Chemical and Materials Sciences, Indian Institute of Technology Goa, Ponda, Goa 403401, India.
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