In this paper, we investigated the threshold voltage () variations in sub 5-nm node silicon nanosheet FETs (NSFETs) caused by Ge and C diffusion into NS channels using fully-calibrated 3-D TCAD simulation. Ge (C) atoms of SiGe (SiC) source/drain (S/D) diffuse toward the NS channels in lateral direction in -type (-type) FETs, and Ge atoms of SiGe stacks diffuse toward the NS channels in vertical direction. Increasing Ge mole fraction of the SiGe S/D in the -type FETs (PFETs) causing increasing compressive channel stress retards boron dopants diffusing from the SiGe S/D into the NS channels, thus increasing the of PFETs (). However, the decreases as the Ge mole fraction of the SiGe S/D becomes greater than 0.5 due to the higher valence band energy () of the NS channels. On the other hand, the of -type FETs (NFETs) () consistently increases as the C mole fraction of the SiC S/D increases due to monotonously retarded phosphorus dopants diffusing from the SiC S/D into the NS channels. On the other hand, the and consistently decreases and increases, respectively, as Si/SiGe intermixing becomes severer because both and conduction band energies () of the NS channels become higher. In addition, the variations are more sensitive to the Si/SiGe intermixing than the variations because the Ge mole fraction in NS channels affects the remarkably rather than the . As a result, the Ge atoms diffusing toward the NS channels should be carefully considered more than the C diffusion toward the NS channels for fine variation optimization in sub 5-nm node NSFETs.
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http://dx.doi.org/10.1166/jnn.2020.17799 | DOI Listing |
Langmuir
January 2025
Key Laboratory of Ocean Energy Utilization and Energy Conservation of Ministry of Education, School of Energy and Power Engineering, Dalian University of Technology, Dalian 116023, P. R. China.
Interfacial tension () between CO and brine depends on chemical components in multiphase systems, intricately evolving with a change in temperature. In this study, we developed a convolutional neural network with a multibranch structure (MBCNN), which, in combination with a compiled data set containing measurement data of 1716 samples from 13 available literature sources at wide temperature and pressure ranges (273.15-473.
View Article and Find Full Text PDFLangmuir
January 2025
Unilever R&D, 40 Merrit Boulevard, Trumbull, Connecticut 06611, United States.
Mixtures of multiple surfactants that have superior performance to the individual components are highly sought-after commercially. Mixtures with a reduced Krafft point () are particularly useful as they enable applications at lower temperatures. Such an example is the soap maker's eutectic: the mixture of sodium laurate (NaL) and sodium oleate (NaOl).
View Article and Find Full Text PDFEnviron Sci Technol
January 2025
Indian Institute of Technology-Delhi (IIT Delhi), Hauz Khas, New Delhi 110016, India.
Observation-based verification of regional/national methane (CH) emission trends is crucial for transparent monitoring and mitigation strategy planning. Although surface observations track the global and sub-hemispheric emission trends well, their sparse spatial coverage limits our ability to assess regional trends. Dense satellite observations complement surface observations, offering a valuable means to validate emission trends, especially in regions where emissions changes are substantial but debated.
View Article and Find Full Text PDFJ Phys Chem B
January 2025
Centre for Lasers & Photonics, Indian Institute of Technology Kanpur, Kanpur, Uttar Pradesh 208016, India.
Nonideality in a binary solvent mixture is manifested through anomalies in various physical properties like viscosity, dielectric constant, polarity, freezing point, boiling point, and so forth. Sometimes, such anomalies become much more prominent, leading to a synergistic behavior, where the physical property of the mixture is way different from its bulk counterparts. Various alcohols/chlorinated methane binary solvent mixtures show such a synergistic behavior.
View Article and Find Full Text PDFMolecules
December 2024
Coimbra Chemistry Center, Institute of Molecular Sciences (CQC-IMS), University of Coimbra, 3004-535 Coimbra, Portugal.
The membrane dipole potential that arises from the interfacial water and constitutive dipolar groups of lipid molecules modulates the interaction of amphiphiles and proteins with membranes. Consequently, its determination for lipid mixtures resembling the existing diversity in biological membranes is very relevant. In this work, the dipole potentials of monolayers, formed at the air-water interface, from pure or mixed lipids (1-palmitoyl-2-oleoyl--glycero-3-phosphocholine (POPC), 1-palmitoyl-2-oleoyl--glycero-3-phosphoethanolamine (POPE), 1-palmitoyl-2-oleoyl--glycero-3-phosphatidyserine (POPS), sphingomyelin (SpM) and cholesterol) were measured and correlated with the mean area per lipid.
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