We systematically investigate the generation of optical chirality patterns by applying the superposition of two waves in three scenarios, namely free-space plane waves, evanescent waves of totally reflected light at dielectric interface and propagating surface plasmon waves on a metallic surface. In each scenario, the general analytical solution of the optical chirality pattern is derived for different polarization states and propagating directions of the two waves. The analytical solutions are verified by numerical simulations. Spatially structured optical chirality patterns can be generated in all scenarios if the incident polarization states and propagation directions are correctly chosen. Optical chirality enhancement can be obtained from the constructive interference of free-space circularly polarized light or enhanced evanescent waves of totally reflected light. Surface plasmon waves do not provide enhanced optical chirality unless the near-field intensity enhancement is sufficiently high. The structured optical chirality patterns may find applications in chirality sorting, chiral imaging and circular dichroism spectroscopy.
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http://dx.doi.org/10.1364/OE.383021 | DOI Listing |
Adv Mater
March 2025
Laboratory of Organic Electronics, Department of Science and Technology (ITN), Linköping University, Norrköping, SE-601 74, Sweden.
Chiral-specific interaction of light with organic materials is important but typically arises from circular polarization-dependent absorption of specific optical transitions, resulting in narrow effective wavelength ranges. This study presents a scalable and universal concept for broadband circular dichroism (CD) enabled by strained conducting polymer thin films that possess in-plane hyperbolic optical behavior (i.e.
View Article and Find Full Text PDFACS Nano
March 2025
Department of Electrical and Computer Engineering, Rice University, 6100 Main Street, Houston,, Texas 77005, United States.
Because of their natural 1D structure combined with intricate chiral variations, carbon nanotubes (CNTs) exhibit various exceptional physical properties, such as ultrahigh thermal conductivity and diameter-dependent electrical behavior, ranging from semiconducting to metallic. While CNTs excel individually at the nanoscale, their 1D and chiral nature can be lost on a macroscopic scale when they are randomly assembled. Therefore, the alignment and organization of CNTs in macroscopic structures is crucial for harnessing their full potential.
View Article and Find Full Text PDFRSC Adv
March 2025
College of Chemical Engineering, Qingdao University of Science and Technology Qingdao 266042 China.
Nickel complexes of chiral spiroBox ligand catalyzed Friedel-Crafts alkylation reaction of indoles with nitroalkenes. Excellent yields (up to 99%) and enantiomeric excess (ee) values (up to 97%) were obtained with a broad scope of substrates. This catalytic system provides a facile synthesis of optically active 2-indolyl-1-nitro derivatives with high yield and enantioselectivity.
View Article and Find Full Text PDFJ Am Chem Soc
March 2025
State Key Laboratory of Precision Spectroscopy, East China Normal University, Shanghai 200241, China.
Elucidating the underlying mechanism of effective chirality and energy transfer processes observed in biological assemblies has cross-disciplinary significance, and it is of special interest in the fields of chemistry and biology due to the pivotal role of chirality in life. Challenges in the field include how to achieve real-time monitoring of the chirality and energy transfer dynamics simultaneously, as well as how to distinguish whether these processes take place in the ground or excited state. Herein, we achieve the first attempt at real-time observation of the concerted ultrafast dynamics between the Förster resonance energy transfer (FRET) and the generation of circularly polarized luminescence (CPL) in the excited state in near-infrared CPL supramolecular nanofibers (SNFs) by using femtosecond time-resolved circularly polarized luminescence (fs-TRCPL) spectroscopy.
View Article and Find Full Text PDFNano Lett
March 2025
College of Chemistry, Zhengzhou University, Zhengzhou 450001, China.
Plasmonic nanohelix arrays, exhibiting strong circular dichroism, are among the most promising optical chiral metamaterials. However, achieving chiral plasmonic effects in the visible range remains challenging with current manufacturing techniques, as it requires structures small enough to resonate at visible wavelengths. Herein, we propose a novel strategy for constructing nanohelix arrays through patch-enthalpy-driven self-confined self-assembly of Janus nanoparticles.
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