We studied the alignment changes of polymer-capped gold nanorods (GNRs@PS) under an applied electric field by visible-near-infrared absorption and small-angle X-ray scattering (SAXS) measurements. Monodispersed GNRs with an aspect ratio of 4.0 were produced by the seed-mediated growth method using cetyltrimethylammonium bromide and sodium oleate binary surfactants. We investigated the phase transition between the ordered structure of GNRs@PS induced by the external electric field. At appropriate field strengths (>3 V/μm), the SAXS profiles of GNRs@PS showed a smectic ordered structure. Increasing the electric field strength densified the ordered structure and greatly increased the Raman signals (the 298 and 445 cm bands) of the carbon tetrachloride (solvent) between the GNRs@PS. The insights gained are potentially applicable to catalysts, future displays, optical filters, and data storage devices.
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