Roll-to-roll printed high voltage supercapattery in lead-contaminated aqueous electrolyte.

Phys Chem Chem Phys

Department of Chemistry, Addis Ababa University, PBox 1176, Addis Ababa, Ethiopia and State Key Laboratory of Luminescent Materials and Devices, Institute of Polymer Optoelectronic Materials and Devices, School of Materials Science and Engineering, South China University of Technology, 381 Wushan Road, Guangzhou, 510640, P. R. China.

Published: March 2020

AI Article Synopsis

  • * The PEDOT:PSS/ITO/PET electrode demonstrated significant performance, achieving a maximum capacitance of 10 μAh cm-2 in a specific solution and maintaining 63% of initial capacitance after 1000 cycles.
  • * A high-voltage device using this electrode was developed, showing energy densities of 6.2 Wh kg-1 in 0.1 M NaCl, which increased to 11 Wh kg-1 with a higher Pb2+ concentration.

Article Abstract

This work investigated the potential application of roll-to-roll printed PEDOT:PSS on an ITO/PET substrate using Pb2+ containing 0.1 M NaCl aqueous solution for a supercapattery. The PEDOT:PSS/ITO/PET electrode achieved 2.2 μAh cm-2 (46.5 mAh g-1) in 0.1 M NaCl and 10 μAh cm-2 (216.8 mAh g-1) in 2 mM Pb2+/0.1 M NaCl at a current density of 0.2 mA cm-2 (4.34 A g-1). The electrode also shows good cyclic performance that retains 63% of its initial capacitance after 1000 charge-discharge cycles. A device operating at a high voltage of 1.8 V was built using PEDOT:PSS/ITO/PET in aqueous electrolyte. The energy density of the symmetric PEDOT:PSS/ITO/PET device is 6.2 Wh kg-1 in 0.1 M NaCl and is improved to 11 Wh kg-1 in 3 mM Pb2+/0.1 M NaCl.

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Source
http://dx.doi.org/10.1039/c9cp06730bDOI Listing

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