In recent years interest in the fate of chemical compounds in the aquatic environment has increased. There are many reports of the presence of chemical compounds such as pesticides, steroid hormones or antibiotics in the aquatic environment. At present, little is known about synthetic organic dyes as contaminants of water bodies. These dyes are omnipresent in many application areas from the textile, tannery, cosmetic and food industries to human and veterinary medicine. Their large-scale production and widespread applications have caused synthetic organic dyes to permeate into different compartments of water and soil environment. So far, dyes have been determined in environmental samples such as water, suspended particulate matters, sediment and wild fish. For this reason, they are considered micropollutants of aquatic ecosystems. Due to the toxicological properties and pharmacological activity of some synthetic organic dyes their occurrence in water bodies should be monitored. The hazard potential of synthetic organic dyes should be assessed, especially their influence on aquatic biota, not least because dyes in water ecosystems may pose a threat to animal or human health as higher-order consumers. This review collects scientific data considering application areas, toxicity, sources, environmental occurrence and the fate of synthetic organic dyes and the ecological implications of synthetic organic dyes presence in the total environment. Moreover, analytical methods for dye determination and methods for dye removal from wastewater are described.
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http://dx.doi.org/10.1016/j.scitotenv.2020.137222 | DOI Listing |
Polymers (Basel)
January 2025
Department of Materials Science and Engineering, Iowa State University, Ames, IA 50011, USA.
This review examines the recent advancements and unique properties of polymer-inorganic hybrid materials formed through coordination bonding (Class II hybrids), which enable enhanced functionality and stability across various applications. Here, we categorize these materials based on properties gained through complexation, focusing on electrical conductivity, thermal stability, photophysical characteristics, catalytic activity, and nanoscale self-assembly. Two major synthetic approaches to making these hybrids include homogeneous and heterogeneous methods, each with distinct tradeoffs: Homogeneous synthesis is straightforward but requires favorable mixing between inorganic and polymer species, which are predominantly water-soluble complexes.
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January 2025
Engelhardt Institute of Molecular Biology of the Russian Academy of Sciences, 32 Vavilov St., Moscow 119991, Russia.
In recent years, a number of synthetic potentiators of antibiotics have been discovered. Their action can significantly enhance the antibacterial effect and limit the spread of antibiotic resistance through inhibition of bacterial cystathionine-γ-lyase. To expand the known set of potentiators, we developed methods for the synthesis of five new representatives of 6-bromoindole derivatives-potential inhibitors of bacterial cystathionine-γ-lyase-namely potassium 3-amino-5-((6-bromoindolyl)methyl)thiophene-2-carboxylate () and its 6-bromoindazole analogs ( and ), along with two 6-broindazole analogs of the parent compound .
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January 2025
Institute of Chemistry and Chemical Technology, Faculty of Natural Sciences and Technology, Riga Technical University, P. Valdena Str. 3, LV-1048 Riga, Latvia.
A metal-free two-step synthetic approach for obtaining indole derivatives from aryl triazole fragment-containing compounds has been developed. In the first step, the Dimroth equilibrium, followed by nitrogen extrusion, Wolff rearrangement, and amine nucleophile addition, leads to the formation of -aryl ethene-1,1-diamines. In the second step, the latter intermediates are cyclized into the target 1-indoles in the presence of iodine.
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January 2025
Department of Chemistry, Texas A&M University, College Station, TX 77842-3012, USA.
Five representatives of a novel type of di(hydroperoxy)alkane adducts of phosphine oxides have been synthesized and fully characterized, including their solubility in organic solvents. The phosphine oxide CyPO () has been used in combination with the corresponding aldehydes to create the adducts CyPO·(HOO)CHCH (), CyPO·(HOO)CHCHCH (), CyPO·(HOO)CH(CH)CH (), CyPO·(HOO)CH(CH)CH (), and CyPO·(HOO)CH(CH)CH (). All adducts crystallize easily and contain the peroxide and phosphine oxide hydrogen-bonded in 1:1 ratios.
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January 2025
School of Pharmaceutical Sciences, Aichi Gakuin University, 1-100 Kusumoto-cho, Chikusa-ku, Nagoya 464-8650, Japan.
Oxazole, a versatile and significant heteroarene, serves as a bridge between synthetic organic chemistry and applications in the medicinal, pharmaceutical, and industrial fields. Polycyclic aromatic compounds with amino groups substituted at the 2-position of an oxazole, such as 2-aminonaphthoxazoles, are expected to be functional probes, but their synthetic methods are extremely limited. Herein, we describe electrochemical reactions of 3-amino-2-naphthol or 3-amino-2-anthracenol and isothiocyanates in DMSO, using a graphite electrode as an anode and a platinum electrode as a cathode in the presence of potassium iodide (KI), which afford -arylnaphtho- and -arylanthra[2,3-]oxazol-2-amines via cyclodesulfurization.
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