Nanosphere lithography: the effect of chemical etching and annealing sequence on the shape and spectrum of nano-metal arrays.

Heliyon

Photonics Group, Research Institute for Applied Physics and Astronomy, University of Tabriz, Tabriz, Iran.

Published: February 2020

In this paper, it is shown that the sequence of chemical etching of the template and annealing has a significant effect on the shape and spectrum of the nano-metal arrays fabricated by nanosphere lithography (NSL). Higher nanoparticles with sharp edges are fabricated as a consequence of annealing the metal coated template, which is a 2d colloidal crystal, before chemical etching. Consequently, the absorption spectra of the fabricated sample become much sharper, in comparison with the one that is fabricated with the reversed order and also a shift is observed in the peak wavelength. The achieved result has practical importance for the applications of these nano-metal arrays in localized surface plasmon resonance (LSPR) based sensors.

Download full-text PDF

Source
http://www.ncbi.nlm.nih.gov/pmc/articles/PMC7016265PMC
http://dx.doi.org/10.1016/j.heliyon.2020.e03382DOI Listing

Publication Analysis

Top Keywords

chemical etching
12
nano-metal arrays
12
nanosphere lithography
8
shape spectrum
8
spectrum nano-metal
8
lithography chemical
4
etching annealing
4
annealing sequence
4
sequence shape
4
arrays paper
4

Similar Publications

Premelted-Substrate-Promoted Selective Etching Strategy Realizing CVD Growth of High-Quality Graphene on Dielectric Substrates.

ACS Appl Mater Interfaces

January 2025

Center for Nanochemistry, Beijing Science and Engineering Center for Nanocarbons, Beijing National Laboratory for Molecular Sciences, College of Chemistry and Molecular Engineering, Peking University, Beijing 100871, China.

Direct chemical vapor deposition growth of high-quality graphene on dielectric substrates is a great challenge. Graphene growth on dielectrics always suffers from the issues of a high nucleation density and poor quality. Herein, a premelted-substrate-promoted selective etching (PSE) strategy was proposed.

View Article and Find Full Text PDF

Construction of CuMoS/ZnO Heterostructures and Mechanism of Photocatalytic Hydrogen Production.

Langmuir

January 2025

Heilongjiang Provincial Key Laboratory of CO2 Resource Utilization and Energy Catalytic Materials, School of Material Science and Chemical Engineering, Harbin University of Science and Technology, Harbin 150040, China.

Constructing wide and narrow band gap heterogeneous semiconductors is a method to improve the activity of photocatalysts. In this paper, CMS/ZnO heterojunctions were prepared by solvothermal loading of ZnO particles on the surface of CuMoS nanosheets. The photocatalytic H precipitation rate is about 545 μmol·g·h, which is 6.

View Article and Find Full Text PDF

A Two-in-One Strategy to Simultaneously Boost the Site Density and Turnover Frequency of Fe-N-C Oxygen Reduction Catalysts.

Angew Chem Int Ed Engl

January 2025

Hunan University, Chemistry and Chemical Engineering, Lushan South Road, Yuelu District, 410082, Changsha, CHINA.

Site density and turnover frequency are the two fundamental kinetic descriptors that determine the oxygen reduction activity of iron-nitrogen-carbon (Fe-N-C) catalysts. However, it remains a grand challenge to simultaneously optimize these two parameters in a single Fe-N-C catalyst. Here we show that treating a typical Fe-N-C catalyst with ammonium iodine (NH4I) vapor via a one-step chemical vapor deposition process not only increases the surface area and porosity of the catalyst (and thus enhanced exposure of active sites) via the etching effect of the in-situ released NH3, but also regulates the electronic structure of the Fe-N4 moieties by the iodine dopants incorporated into the carbon matrix.

View Article and Find Full Text PDF

Boosting the Hydrogen Evolution Activity of a Low-Coordinated Co─N─C Catalyst via Vacancy Defect-Mediated Alteration of the Intermediate Adsorption Configuration.

Adv Sci (Weinh)

January 2025

State Key Laboratory for Chemo/Biosensing and Chemometrics, Advanced Catalytic Engineering Research Center of the Ministry of Education and College of Chemistry and Chemical Engineering, Hunan University, Changsha, 410082, P. R. China.

The cobalt-nitrogen-carbon (Co─N─C) single-atom catalysts (SACs) are promising alternatives to precious metals for catalyzing the hydrogen evolution reaction (HER) and their activity is highly dependent on the coordination environments of the metal centers. Herein, a NaHCO etching strategy is developed to introduce abundant in-plane pores within the carbon substrates that further enable the construction of low-coordinated and asymmetric Co─N sites with nearby vacancy defects in a Co─N─C catalyst. This catalyst exhibits a high HER activity with an overpotential (η) of merely 78 mV to deliver a current density of 10 mA cm, a Tafel slope of 45.

View Article and Find Full Text PDF

Background: Bee venom consists of more than 50 % melittin (MLT), which has anti-cancer, anti-inflammatory, and antimicrobial properties. Bee venom also contains toxic components such as phospholipase A2 (PLA2) and hyaluronidase (HYA), which cause allergic reactions, so the toxic components must be removed to use MLT. In previous studies, analytical methods were used to separate MLT.

View Article and Find Full Text PDF

Want AI Summaries of new PubMed Abstracts delivered to your In-box?

Enter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!