In this work, we model and simulate the shape evolution of critically charged droplets, from the initial spherical shape to the charge emission and back to the spherical shape. The shape deformation is described using the viscous correction for viscous potential flow model, which is a potential flow approximation of the Navier-Stokes equation for incompressible Newtonian fluids. The simulated shapes are compared to snapshots of experimentally observed drop deformations. We highlight the influence of the dimensionless viscosity and charge carrier mobility of the liquid on the shape evolution of droplets and discuss the observed trends. We give an explanation as to why the observed deformation pathways of positively and negatively charged pure water droplets differ and give a hint as to why negatively charged water droplets emit more charge during charge breakup than positively charged ones.
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http://dx.doi.org/10.1103/PhysRevE.101.013105 | DOI Listing |
Adv Colloid Interface Sci
December 2024
Jerzy Haber Institute of Catalysis and Surface Chemistry, Polish Academy of Sciences, Niezapominajek 8, PL-30239 Krakow, Poland. Electronic address:
Chitosan, a biocompatible polysaccharide, finds a wide range of applications, inter alia as an antimicrobial agent, stabilizer of food products, cosmetics, and in the targeted delivery of drugs and stem cells. This work represents a comprehensive review of the properties of chitosan molecule and its aqueous solutions uniquely combining theoretical modeling and experimental results. The emphasis is on physicochemical aspects which were sparsely considered in previous reviews.
View Article and Find Full Text PDFGels
December 2024
Horváth Csaba Memorial Laboratory of Bioseparation Sciences, Research Center for Molecular Medicine, Faculty of Medicine, Doctoral School of Medicine, University of Debrecen, 4032 Debrecen, Hungary.
Hydrogels like agarose have long been used as sieving media for the electrophoresis-based analysis of biopolymers. During gelation, the individual agarose strands tend to form hydrogen-bond mediated double-helical structures, allowing thermal reversibility and adjustable pore sizes for molecular sieving applications. The addition of tetrahydroxyborate to the agarose matrix results in transitional chemical cross-linking, offering an additional pore size adjusting option.
View Article and Find Full Text PDFGels
November 2024
Physics Department, Lomonosov Moscow State University, 119991 Moscow, Russia.
Bio-based eco-friendly cellulose nanocrystals (CNCs) gain an increasing interest for diverse applications. We report the results of an investigation of hydrogels spontaneously formed by the self-assembly of carboxylated CNCs in the presence of CaCl using several complementary techniques: rheometry, isothermal titration calorimetry, FTIR-spectroscopy, cryo-electron microscopy, cryo-electron tomography, and polarized optical microscopy. Increasing CaCl concentration was shown to induce a strong increase in the storage modulus of CNC hydrogels accompanied by the growth of CNC aggregates included in the network.
View Article and Find Full Text PDFJ Colloid Interface Sci
December 2024
Department of Chemical and Biomolecular Engineering, Case School of Engineering, Case Western Reserve University, Cleveland, OH 44106, United States.
We present a study combining experimental measurements, theoretical analysis, and simulations to investigate core-shell microcapsules interacting with a solid boundary, with a particular focus on understanding the short-range potential energy well arising from the tethered force. The microcapsules, fabricated using a Pickering emulsion template with a cinnamon oil core and calcium alginate shell, were characterized for size (∼5-6μm in diameter) and surface charge (∼-20mV). We employed total internal reflection microscopy and particle tracking to measure the microcapsule-boundary interactions and diffusion, from which potential energy and diffusivity profiles were derived.
View Article and Find Full Text PDFDrug Dev Ind Pharm
November 2024
Department of Pharmaceutics, College of Pharmacy, Qassim University, Qassim, Saudi Arabia.
Background: Due to the toxicity and serious side effects of chemical incorporated in topical dosage form used for treatment of wound healing, there is a need to use natural preparation as wound healing preparation.
Aims: Seeds of (TFG) are used to synthesize eco-friendly silver nanoparticles (SNPs) in an appropriate way to heal wounds.
Methods: To synthesize SNPs, TFG was incubated with AgNO to produce SNP-TFG.
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