AI Article Synopsis

  • The self-assembly of leucoquinizarin molecules on gold surfaces primarily occurs in a keto-enolic tautomeric form, indicating a dominant configuration.
  • Evidence suggests that these molecules can temporarily switch to other tautomeric forms, showing variability in their structure.
  • This metastable chemistry could be leveraged for creating more complex organic interfaces in future applications.

Article Abstract

The self-assembly of leucoquinizarin molecules on Au(111) surfaces is shown to be characterized by the molecules mostly being in their keto-enolic tautomeric form, with evidence of their temporary switching to other tautomeric forms. This reveals a metastable chemistry of the assembled molecules, to be considered for their possible employment in the formation of more complex hetero-organic interfaces.

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Source
http://dx.doi.org/10.1039/c9cc09915hDOI Listing

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