Approaches to mid-infrared, super-resolution imaging and spectroscopy.

Phys Chem Chem Phys

Department of Chemistry and Biochemistry, University of Notre Dame, Notre Dame, IN 46556, USA. and Department of Physics, University of Notre Dame, Notre Dame, IN 46556, USA.

Published: February 2020

This perspective highlights recent advances in super-resolution, mid-infrared imaging and spectroscopy. It provides an overview of the different near field microscopy techniques developed to address the problem of chemically imaging specimens in the mid-infrared "fingerprint" region of the spectrum with high spatial resolution. We focus on a recently developed far-field optical technique, called infrared photothermal heterodyne imaging (IR-PHI), and discusses the technique in detail. Its practical implementation in terms of equipment used, optical geometries employed, and underlying contrast mechanism are described. Milestones where IR-PHI has led to notable advances in bioscience and materials science are summarized. The perspective concludes with a future outlook for robust and readily accessible high spatial resolution, mid-infrared imaging and spectroscopy techniques.

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http://dx.doi.org/10.1039/c9cp05815jDOI Listing

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