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Potential physiological tolerance mechanisms in faba bean to spp. parasitism.
Front Plant Sci
December 2024
Field Crops Laboratory, National Institute for Agricultural Research of Tunisia (INRAT), Carthage University, Ariana, Tunisia.
spp. are root parasitic plants that cause severe yield losses in faba bean ( L.).
View Article and Find Full Text PDFGiant {Mo} polyoxometalate isolated with diverse organic cations: a systematic proton conductivity study.
Dalton Trans
December 2024
School of Chemistry, University of Hyderabad, Hyderabad - 500046, India.
The development of efficient and stable proton conductors is a pivotal area of research due to their transformative potential in alternative energy technologies. Recently, there has been a surge of interest in synthesizing proton conductors based on polyoxometalate (POM) materials, attributed to their highly negatively charged and oxygen-rich surfaces. In this study, we report on a highly water-soluble giant POM, (NH)[MoO(CHCOO)(HO)]·300HO·10CHCOONH (designated as {Mo}), which was rendered insoluble in water by exchanging its ammonium cations with larger organic cations, specifically histidinium, pyridinium, bipyridinium, and methyl viologen, resulting in His-Mo132, Py-Mo132, Bpy-Mo132 and MV-Mo132, respectively.
View Article and Find Full Text PDFIntroduction: Aviation safety sensitive personnel (SSP) function in highly complex environments. SSP mental health is thought to support safety, efficiency, and overall health. Research is needed to identify how to optimize and screen mental health across aviation SSP, but no consensus exists on the research priorities that need to be met.
View Article and Find Full Text PDFICT-based fluorescent nanoparticles for selective cyanide ion detection and quantification in apple seeds.
Analyst
December 2024
Department of Chemistry, Khalifa University of Science and Technology, Abu Dhabi, P.O. Box 127788, United Arab Emirates.
In this report, we successfully engineered a novel probe based on an acceptor-donor-acceptor (A-D-A) architecture featuring dicyanovinyl-substituted thieno[3,2-]thiophene, termed DCVTT. The designed probe self-assembles into luminous nanoparticles (DCVTT NPs) upon introducing mixed aqueous solutions. These fluorescent nanostructures served as a ratiometric probe for detecting cyanide (CN) ions in aqueous-based environments, owing to the robust Intramolecular Charge Transfer (ICT) characteristics of DCVTT.
View Article and Find Full Text PDFCatalyst-free coupling of peroxypyrroloindolenines with amines to afford stable peroxyindolenines.
Org Biomol Chem
December 2024
Key Laboratory of Molecule Synthesis and Function Discovery (Fujian Province University), College of Chemistry, Fuzhou University, Fuzhou, Fujian 350116, China.
Here we report a highly efficient method for coupling of peroxypyrroloindolenines with amines under catalyst-free conditions to obtain stable C2-N peroxyindolenines in high yields with remarkable functional group tolerance. Initial studies have shown that compound 13 exhibits potent inhibition of the B16/F10 cell line with an IC value of 2.18 μM.
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