The copper-catalyzed azide-alkyne cycloaddition (CuAAC) click reaction is among the most extensively used strategies for the post-polymerization modification of COFs. This work shows a new procedure for the postsynthetic functionalization of imine-based COFs by using a heterogeneous solid-gas reaction between alkyne-functionalized COFs and azides in the absence of a copper catalyst. This new alternative represents a step forward towards a greener postsynthetic modification of COFs opening a high potential for the development of new applications.
Download full-text PDF |
Source |
|---|---|
| http://dx.doi.org/10.1002/chem.202000224 | DOI Listing |
Publication Analysis
Top Keywords
postsynthetic modification
8
modification cofs
8
gas-solid heterogeneous
4
heterogeneous postsynthetic
4
modification imine-based
4
imine-based covalent
4
covalent organic
4
organic frameworks
4
frameworks copper-catalyzed
4
copper-catalyzed azide-alkyne
4
Similar Publications
Want AI Summaries of new PubMed Abstracts delivered to your In-box?
Enter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!