A new bis-hydroxyphenylpyrazolyl ligand, HL, allows isolating and structurally characterizing vanadyl and titanyl dinuclear complexes (BuN)[(MO)(HL)] (M = V, Ti). The weak dipolar coupling and relatively short quantum coherence of the divanadyl anions are optimal for a 2-qubit molecular architecture proposed to implement electron-mediated nuclear quantum simulations.
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A bis-vanadyl coordination complex as a 2-qubit quantum gate.
Chem Commun (Camb)
March 2020
Departament de Química Inorgànica i Orgànica, Universitat de Barcelona, Diagonal 645, 08028 Barcelona, Spain. guillem.aromi.qi.ub.es.
A new bis-hydroxyphenylpyrazolyl ligand, HL, allows isolating and structurally characterizing vanadyl and titanyl dinuclear complexes (BuN)[(MO)(HL)] (M = V, Ti). The weak dipolar coupling and relatively short quantum coherence of the divanadyl anions are optimal for a 2-qubit molecular architecture proposed to implement electron-mediated nuclear quantum simulations.
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