Ethylenediamine-assisted growth of multi-dimensional ZnS nanostructures and study of its charge transfer mechanism on supercapacitor electrode and photocatalytic performance.

In recent years, much interest has been raised by materials with multi-purpose characteristics as the performance of electrochemical energy devices such as supercapacitors and photocatalytic activities depend strongly on the properties of materials. This study delineates various parameters like morphology, energy band gap, charge transfer resistance, different defect states, diffusion coefficient and functional groups adsorbed on the surface of material to assess the performance of supercapacitor electrodes and photocatalytic degradation efficiency of synthesised multi-dimensional ZnS nanostructures. Ethylenediamine (EN)-mediated multi-dimensional ZnS nanostructures were grown by the solvothermal route. One-dimensional (1D), 2D and 3D morphologies were obtained by varying the ratio of de-ionised water and EN, taken as 1:3, 1:2 and 1:1, respectively. The EN molecules effectively capped most of the surfaces of the ZnS nanoparticles formed, preventing agglomeration of nanoparticles due to the decrement in surface energy. The oriented attachment of these clusters resulted in the formation of 1D, 2D and 3D morphologies. The plausible chemistry in the formation of 1D, 2D and 3D nanostructures has been elaborated. Charge transfer properties of prepared electrodes have been examined using the electrochemical impedance spectroscopy (EIS) technique because better charge transfer causes diminishing electron/hole recombination and hence better photodegradation efficiency. Among the synthesised materials, the 2D nanostructure degraded the eosin Y dye to maximum 90.71% efficiency with rate constant 34 × 10 min. 2D nanostructures possess better charge transfer and hence better photodegradation efficiency. Various studies using methods of UV-vis, Fourier-transform infrared, Brunauer-Emmett-Teller, x-ray photoelectron spectroscopy and photoluminescence spectra are in good agreement with the obtained photodegradation results. After analysing cyclic voltammetry curves and EIS, a higher diffusion coefficient is obtained for 1D nanostructure material, hence a higher specific capacitance and higher energy density of 159.12 F g and 22.75 KWh kg are found in this case. Only 9% loss of specific capacitance is found after 1000 cycles, showing a relatively high cycling stability in 3D nanostructures. The excellent supercapacitive property can be attributed to the porous structure and high specific surface area. Thus, the synthesised multi-dimensional ZnS nanostructures are proved to be a potential candidate for both photocatalytic and supercapacitor electrode performance.