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Asymmetric ketone hydroboration catalyzed by alkali metal complexes derived from BINOL ligands. | LitMetric

Asymmetric ketone hydroboration catalyzed by alkali metal complexes derived from BINOL ligands.

Dalton Trans

Cardiff Catalysis Institute, School of Chemistry, Cardiff University, Main Building, Park Place, Cardiff, CF10 3AT, Cymru/Wales, UK.

Published: February 2020

AI Article Synopsis

Article Abstract

The ability of alkali metal complexes featuring functionalized BINOL-derived ligands to catalyze ketone hydroboration reactions was explored. The reduced products were formed in excellent yields and with variable enantioselectivities dependent upon the nature of the ligand and the alkali metal cation.

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Source
http://dx.doi.org/10.1039/d0dt00232aDOI Listing

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