Nowadays, it is highly desired to develop dual-modal fluorescence and magnetic resonance imaging (FI/MRI) probes in medical imaging because it unites the respective advantages of each imaging modality: high sensitivity of FI and superior spatial resolution of MRI. In this study, a facile strategy to fabricate a new bimodal imaging nanoprobe (Gd-CQDs@N-FeO) was reported by integrating the fluorescence ability of carbon quantum dots (CQDs) and T and T contrast-enhancing functionality of Gd(III) ions and FeO nanoparticles into a single hybrid nanostructure. The hybrid composites were investigated by FT-IR, XRD, TEM, XPS, VSM, and so on, which confirmed that Gd-CQDs@N-FeO nanoparticles were successfully obtained and exhibited superparamagnetic property at room temperature. The derived nanoprobes presented an excitation wavelength-independent emission behavior. In addition, r and r relaxivities of the synthesized imaging nanoprobes were measured to be 5.16 and 115.6 mM s, which nominated Gd-CQDs@N-FeO nanocomposites as a suitable T-T contrast agent. The Gd-CQDs@N-FeO nanoparticles combining two synergetic imaging modalities showed great potential in FI/MRI dual-modal imaging for a more complementary and accurate detection.
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http://dx.doi.org/10.1016/j.mri.2020.02.003 | DOI Listing |
Environ Sci Process Impacts
January 2025
Department of Civil, Environmental and Architectural Engineering, University of Colorado at Boulder, Boulder, 80309, USA.
Wildfires can severely degrade soils and watersheds. Post-fire rain events can leach ashes and altered dissolved organic matter (DOM) into streams, impacting water quality and carbon biogeochemistry. The photochemical properties and persistence of DOM from wildfire ash leachates are not well understood.
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January 2025
Key Laboratory for Photonic and Electronic Bandgap Materials, Ministry of Education, School of Physics and Electronic Engineering, Harbin Normal University, Harbin 150025, People's Republic of China.
A binder-free and freestanding electrode was designed by uniformly immobilizing carbon quantum dot (CQD)-anchored polyaniline (PANI) heterostructures onto electrospun carbon nanofibers (CNFs) a facile hierarchical assembly process. The fabricated freestanding CNF/PANI/CQD electrode exhibits a unique three-dimensional (3D) network nanostructure, which accelerates ion migration between the interior and surface of the electrode, thereby enhancing its charging and discharging performance. Moreover, the functional groups on the surface of CQDs could anchor PANI through possible chemical bonding, which not only improves the stability of the PANI/CQD heterojunction but also creates an additional conductive channel for the PANI polymer.
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January 2025
Department of Chemistry and Biochemistry, University of California San Diego, La Jolla, California 92093, United States.
In quantum information science and sensing, electron spins are often purified into a specific polarization through an optical-spin interface, a process known as optically detected magnetic resonance (ODMR). Diamond-NV centers and transition metals are both excellent platforms for these so-called color centers, while metal-free molecular analogues are also gaining popularity for their extended polarization lifetimes, milder environmental impacts, and reduced costs. In our earlier attempt at designing such organic high-spin π-diradicals, we proposed to spin-polarize by shelving triplet = ±1 populations as singlets.
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January 2025
Instituto de Física, Universidade Federal de Goiás, Goiânia, Goiás 74001-970, Brazil.
We investigate the energetic and structural properties of small lithium clusters doped with a carbon atom using a combination of computational methods, including density functional theory (DFT), diffusion quantum Monte Carlo (DMC), and the Hartree-Fock (HF) approximation. We calculate the lowest energy structures, total ground-state energies, electron populations, binding energies, and dissociation energies as a function of cluster size. Our results show that carbon doping significantly enhances the stability of lithium clusters, increasing the magnitude of the binding energy by 0.
View Article and Find Full Text PDFChemphyschem
January 2025
Chinese Academy of Sciences, Institute of Coal Chemistry, 27 South Taoyuan Road, Taiyuan, Shanxi, P.R.China, 030001, Taiyuan, CHINA.
Electric double layer capacitors (EDLC) require large specific surface area to provide high power density. The generation of pores increases the electrochemical capacitance with more graphitic edge planes exposed to the electrolyte. Conventional theory believes this increasing in capacitance is owed to the increased specific surface area, but our work uncovers another mechanism.
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