Robust field-dressed spectra of diatomics in an optical lattice.

Phys Chem Chem Phys

Department of Theoretical Physics, University of Debrecen, H-4002 Debrecen, PO Box 400, Hungary. and ELI-ALPS, ELI-HU Non-Profit Ltd, H-6720 Szeged, Dugonics tér 13, Hungary.

Published: February 2020

The absorption spectra of the cold Na molecule dressed by a linearly polarized standing laser wave is investigated with a theoretical model incorporating translational, electronic, vibrational as well as rotational degrees of freedom. In such a situation a light-induced conical intersection (LICI) can be formed (J. Phys. B: At. Mol. Opt. Phys., 2008, 41, 221001). To measure the spectra a weak field is used whose propagation direction is perpendicular to the direction of the dressing field but has identical polarization direction. Although LICIs are present in our model, the simulations demonstrate a very robust absorption spectrum, which is insensitive to the intensity and the wavelength of the dressing field and which does not reflect clear signatures of light-induced nonadiabatic phenomena related to the strong mixing between the electronic, vibrational, rotational and translational motions. However, by widening artificially the very narrow translational energy level gaps, the fingerprint of the LICI appears to some extent in the spectrum.

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Source
http://dx.doi.org/10.1039/c9cp06587cDOI Listing

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