One-pot aerobic oxidative sulfonamidation of aromatic thiols with ammonia by a dual-functional β-MnO nanocatalyst.

Chem Commun (Camb)

Laboratory for Materials and Structures, Institute of Innovative Research, Tokyo Institute of Technology, 4259 Nagatsuta-cho, Midori-ku, Yokohama 226-8503, Japan.

Published: February 2020

High-surface-area β-MnO2 (β-MnO2-HS) nanoparticles could act as effective heterogeneous catalysts for the one-pot oxidative sulfonamidation of various aromatic and heteroaromatic thiols to the corresponding sulfonamides using molecular oxygen (O2) and ammonia (NH3) as respective oxygen and nitrogen sources, without the need for any additives.

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http://dx.doi.org/10.1039/c9cc09411cDOI Listing

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