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Carbon-Phosphorus Coupling from C^N Cyclometalated Au Complexes. | LitMetric
With the aim of exploiting new organometallic species for cross-coupling reactions, we report here on the Au -mediated C -P bond formation occurring upon reaction of C^N cyclometalated Au complexes with phosphines. The [Au(C^N)Cl ] complex 1 featuring the bidentate 2-benzoylpyridine (C N) scaffold was found to react with PTA (1,3,5-triaza-7-phosphaadamantane) under mild conditions, including in water, to afford the corresponding phosphonium 5 through C-P reductive elimination. A mechanism is proposed for the title reaction based on in situ P{ H} NMR and HR-ESI-MS analyses combined with DFT calculations. The C-P coupling has been generalized to other C^N cyclometalated Au complexes and other tertiary phosphines. Overall, this work provides new insights into the reactivity of cyclometalated Au compounds and establishes initial structure-activity relationships to develop Au -mediated C-P cross-coupling reactions.
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