-Perfluoropyridin-4-yl group was first installed onto cycloketone oximes as a new electrophore, which was proven to be efficient iminyl radical precursors under photocatalytic and thermal conditions. A range of -perfluoropyridin-4-yl oximes were successfully utilized in C(sp)-C(sp) bond formations of quinoxalin-2(1)-ones and alkenes, providing facile accesses to a range of functionalized alkylnitriles.
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| http://dx.doi.org/10.1021/acs.joc.9b03251 | DOI Listing |
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