An intrinsic exciton dephasing is the coherence loss of exciton dipole oscillation, while the total exciton dephasing originates from coherence loss due to exciton-exciton interaction and excitonphonon coupling. In this article, the total exciton dephasing time of tungsten diselenide (WSe₂) atomic layers was analyzed as functions of excitation intensity with exciton-exciton coupling strength and temperature with exciton-phonon coupling strength. It was hypothesized that the total exciton dephasing time is shortened as the exciton-exciton interaction and the exciton-phonon coupling are increased. The coherence loss analysis revealed that the exciton dephasing time of WSe₂ atomic layers is due to mainly the temperature rather than the excitation intensity.
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http://dx.doi.org/10.1166/jnn.2020.17593 | DOI Listing |
Nanophotonics
June 2024
Department of Materials Science and Engineering, Rensselaer Polytechnic Institute, Troy, NY, USA.
Exciton-polariton condensates, due to their nonlinear and coherent characteristics, have been employed to construct spin Hamiltonian lattices for potentially studying spin glass, critical dephasing, and even solving optimization problems. Here, we report the room-temperature polariton condensation and polaritonic soft-spin XY Hamiltonian lattices in an organic-inorganic halide perovskite microcavity. This is achieved through the direct integration of high-quality single-crystal samples within the cavity.
View Article and Find Full Text PDFNanophotonics
February 2024
Faculty of Physics, University of Warsaw, ul. Pasteura 5, 02-093 Warszawa, Poland.
We present femtosecond pump-probe measurements of neutral and charged exciton optical response in monolayer MoSe to resonant photoexcitation of a given exciton state in the presence of 2D electron gas. We show that creation of charged exciton (X) population in a given K, K valley requires the capture of available free carriers in the opposite valley and reduces the interaction of neutral exciton (X) with the electron Fermi sea. We also observe spectral broadening of the X transition line with the increasing X population caused by efficient scattering and excitation induced dephasing.
View Article and Find Full Text PDFJ Chem Phys
November 2024
Faculty of Mathematics and Physics, Charles University, Ke Karlovu 5, 121 16 Prague 2, Czech Republic.
Nanoscale
November 2024
P.N. Lebedev Physical Institute of the Russian Academy of Sciences, 119991 Moscow, Russia.
The coherent spin dynamics of electrons and holes in CsPbI perovskite nanocrystals in a glass matrix are studied by the time-resolved Faraday ellipticity technique in magnetic fields up to 430 mT across a temperature range from 6 K to 120 K. The Landé -factors and spin dephasing times are evaluated from the observed Larmor precession of electron and hole spins. The nanocrystal size in the three studied samples varies from about 8 to 16 nm, resulting in exciton transition varying from 1.
View Article and Find Full Text PDFJ Chem Theory Comput
November 2024
High Performance Artificial Intelligence Systems Research Team, RIKEN Center for Computational Science, 7 Chome-1-26 Minatojima Minamimachi, Kobe, Hyogo 650-0047, Japan.
Radical pairs (electron-hole pairs, polaron pairs) are transient reaction intermediates that are found and exploited in all areas of science, from the hard realm of physics in the form of organic semiconductors, spintronics, quantum computing, and solar cells to the soft domain of chemistry and biology under the guise of chemical reactions in solution, biomimetic systems, and quantum biology. Quantitative analysis of radical pair phenomena has historically been successful by a few select groups. With this in mind, we present an intuitive open-source framework in the Python programming language that provides classical, semiclassical, and quantum simulation methodologies.
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