A relationship between stability and self-optimization is found for weakly dissipative heat devices. The effect of limited control on operation variables around an steady state is such that, after instabilities, the paths toward relaxation are given by trajectories stemming from restitution forces which improve the system thermodynamic performance (power output, efficiency, and entropy generation). Statistics over random trajectories for many cycles shows this behavior as well. Two types of dynamics are analyzed, one where an stability basin appears and another one where the system is globally stable. Under both dynamics there is an induced trend in the control variables space due to stability. In the energetic space this behavior translates into a preference for better thermodynamic states, and thus stability could favor self-optimization under limited control. This is analyzed from the multiobjective optimization perspective. As a result, the statistical behavior of the system is strongly influenced by the Pareto front (the set of points with the best compromise between several objective functions) and the stability basin. Additionally, endoreversible and irreversible behaviors appear as very relevant limits: The first one is an upper bound in energetic performance, connected with the Pareto front, and the second one represents an attractor for the stochastic trajectories.
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http://dx.doi.org/10.1103/PhysRevE.100.062128 | DOI Listing |
J Agric Food Chem
March 2025
State Key Laboratory of Agricultural Products Safety/Key Laboratory of Detection for Pesticide Residues and Control of Zhejiang, Institute of Agro-product Safety and Nutrition, Zhejiang Academy of Agricultural Sciences, Hangzhou 310021, P. R. China.
Mefentrifluconazole was the first novel isopropyl alcohol triazole fungicide. Existing research indicated that mefentrifluconazole had high activity and low toxicity, presenting potential for monocase application, while limited data existed on its enantioselective dissipation in crops. Here, after confirming the absolute configuration, the enantioselective dissipation and risk assessments of chiral mefentrifluconazole in soybeans, peanuts, tomatoes, grapes, and soil were conducted.
View Article and Find Full Text PDFGac Sanit
March 2025
Financial Economics and Accounting Department, University of Alicante, Alicante, Spain.
Objective: To review several behavioral economics-based interventions ("healthy nudges") aimed at mitigating the overuse and underuse of healthcare resources -phenomena associated with poorer health outcomes and increased costs.
Method: A comparative case study approach is used to assess the effectiveness of ten studies designed to improve treatment adherence and prevent underuse, as well as those focused on improving prescribing practices to address overuse.
Results: First, healthy nudges are generally effective, although there is considerable variability in their outcomes.
Expert Rev Anti Infect Ther
March 2025
Division of Infectious Diseases and International Health, Duke University Medical Center, Durham, NC, USA.
Introduction: Despite the crucial importance of effective AFS in resource-limited settings, such settings remain comparatively underserved and underrepresented in terms of resource-setting-specific guidance and research. Further practical contextualization and application of current AFS best practices is thus necessary.
Areas Covered: A panel of leading experts from diverse countries (India, Nigeria, Spain, and the US) was brought together to provide recommendations for practical and effective implementation of AFS in resource-limited settings.
Background: Oral language skills are a critical foundation for education and psychosocial development. Learning to read, in particular, depends heavily on oral language skills. The Nuffield Early Language Intervention (NELI) has been shown to improve the language of 4-5-year-old children entering school with language weaknesses in four robust trials.
View Article and Find Full Text PDFAnal Chim Acta
May 2025
Department of Chemistry, Texas A&M University, 580 Ross St., College Station, TX, 77843, USA. Electronic address:
Background: Microdroplets have emerged as effective confined-volume reactors due to their remarkable ability to accelerate chemical reactions compared to bulk systems. Recent research highlights the crucial role of air-liquid interfaces in this acceleration. A microdroplet can be viewed as having two kinetically distinct regions: the interface and the interior.
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