One-pot synthesis has been developed for 4-carboethoxybenzo[]coumarins starting from α-/β-naphthols. Accordingly, diverse 4-carboethoxybenzocoumarins can be synthesized in moderate-to-excellent (31-75%) isolated yields. The synthesis involves initial oxidation of naphthols to the intermediary 1,2-naphthoquinones with 2-iodoxybenzoic acid followed by a cascade of reactions, namely, Wittig olefination, Michael addition, β-elimination, and cyclization. Furthermore, we have comprehensively investigated the excited-state properties of differently substituted 4-carboalkoxybenzo[]coumarins. It is shown that they exhibit low to high fluorescence quantum yields (1-36%) and excited-state lifetimes (ca. 1-7 ns) depending on the substitution pattern and solvent employed.
Download full-text PDF |
Source |
|---|---|
| http://www.ncbi.nlm.nih.gov/pmc/articles/PMC6963932 | PMC |
| http://dx.doi.org/10.1021/acsomega.9b02489 | DOI Listing |
Publication Analysis
Top Keywords
Similar Publications
One-Pot Synthesis of Oxygen Vacancy-Rich Amorphous/Crystalline Heterophase CaWO Nanoparticles for Enhanced Radiodynamic-Immunotherapy.
Adv Sci (Weinh)
December 2024
New Cornerstone Science Laboratory, MOE Key Laboratory for Analytical Science of Food Safety and Biology, College of Chemistry, Fuzhou University, Fuzhou, 350108, China.
Radiodynamic therapy that employs X-rays to trigger localized reactive oxygen species (ROS) generation can tackle the tissue penetration issue of phototherapy. Although calcium tungstate (CaWO) shows great potential as a radiodynamic agent benefiting from its strong X-ray absorption and the ability to generate electron-hole (e-h) pairs, slow charge carrier transfer and fast e-h recombination greatly limit its ROS-generating performance. Herein, via a one-pot wet-chemical method, oxygen vacancy-rich amorphous/crystalline heterophase CaWO nanoparticles (Ov-a/c-CaWO NPs) with enhanced radiodynamic effect are synthesized for radiodynamic-immunotherapy of cancer.
View Article and Find Full Text PDFA novel recyclable hydrolyzed nanomagnetic copolymer catalyst for green, and one-pot synthesis of tetrahydrobenzo[b]pyrans.
Sci Rep
December 2024
Department of Organic Chemistry, Faculty of Chemistry, University of Mazandaran, Babolsar, Iran.
Polymer-based catalysts have garnered significant interest for their efficiency, reusability, and compatibility with various synthesis processes. In catalytic applications, polymers offer the advantage of structural versatility, enabling functional groups to be tailored for specific catalytic activities. In this study, we developed a novel magnetic copolymer of methyl methacrylate and maleic anhydride (PMMAn), synthesized via in situ chemical polymerization of methyl methacrylate onto maleic anhydride, using benzoyl peroxide as a free-radical initiator.
View Article and Find Full Text PDFNanodots of Transition Metal Sulfides, Carbonates, and Oxides Obtained Through Spontaneous Co-Precipitation with Silica.
Nanomaterials (Basel)
December 2024
Material Science, BASF SE, RGA/BM-B007, Carl-Bosch-Str. 38, D-67056 Ludwigshafen, Germany.
The controlled formation and stabilization of nanoparticles is of fundamental relevance for materials science and key to many modern technologies. Common synthetic strategies to arrest growth at small sizes and prevent undesired particle agglomeration often rely on the use of organic additives and require non-aqueous media and/or high temperatures, all of which appear critical with respect to production costs, safety, and sustainability. In the present work, we demonstrate a simple one-pot process in water under ambient conditions that can produce particles of various transition metal carbonates and sulfides with sizes of only a few nanometers embedded in a silica shell, similar to particles derived from more elaborate synthesis routes, like the sol-gel process.
View Article and Find Full Text PDFBoldenone and Testosterone Production from Phytosterol via One-Pot Cascade Biotransformations.
J Fungi (Basel)
November 2024
Federal Research Center, Pushchino Center for Biological Research of Russian Academy of Sciences, G.K. Skryabin Institute of Biochemistry and Physiology of Microorganisms, Prospekt Nauki, 5, 142290 Pushchino, Moscow Region, Russia.
Testosterone (TS) and its 1(2)-dehydrogenated derivative boldenone (BD) are widely used in medicine, veterinary science and as precursors in organic synthesis of many therapeutic steroids. Green production of these compounds is possible from androstenedione (AD) enzymatically, or from phytosterol (PS) using fermentation stages. In this study, the ascomycete sp.
View Article and Find Full Text PDFFull Color Al-Doped InP Quantum Dots with High Brightness via Gram-Scale One-Pot Synthesis for White Light-Emitting Diodes.
ACS Appl Mater Interfaces
December 2024
College of Chemistry and Molecular Sciences, Wuhan University, Wuhan 430072, P. R. China.
High-performance, environmentally friendly indium phosphide (InP)-based quantum dots (QDs) are urgently needed to meet the demands of rapidly evolving display and lighting technologies. By adopting the highly efficient and cost-effective one-pot method and utilizing aluminum isopropoxide (AIP) as the Al source, a series of Al-doped InP/(Al)ZnS QDs with emission maxima ranging from 480 to 627 nm were synthesized. The photoluminescence quantum yield (PLQY) of the blue, green, yellow, orange, and red QDs, with emission peaks at 480, 509, 560, 600, and 627 nm, reached 34%, 62%, 86%, 96%, and 85%, respectively.
View Article and Find Full Text PDFWant AI Summaries of new PubMed Abstracts delivered to your In-box?
Enter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!