Recently, two-dimensional MXenes and MXene-based nanocomposites have become the most important electrode materials because of their unique physical and chemical characteristics. As the electrode of a lithium-ion capacitor, MXenes have exhibited metallic conductivity and plastic layer structure that provide more chemically active interfaces and shortened ion-diffusion lengths, and thus the unbalanced ion kinetics between the anode and cathode can be effectively alleviated. In order to further improve the electrochemical performance of MXenes, the composition, morphology and texture, surface chemistry, and structural configuration of MXenes are extensively investigated. In this mini-review, some recent research and progress of MXenes and MXene-based nanocomposites in lithium-ion capacitors are summarized, which focus on their nanostructure designs and chemical preparation methods, such as prepillaring MXenes, delaminated MXenes, and MXene-based hybrids. Finally, some future perspectives and critical challenges of MXene-based material for lithium-ion capacitor application are also presented and briefly discussed.
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http://dx.doi.org/10.1021/acsomega.9b03662 | DOI Listing |
J Colloid Interface Sci
January 2025
College of Chemical and Pharmaceutical Engineering, Jilin Institute of Chemical Technology, Jilin 132022, PR China. Electronic address:
MoCT MXenes have great potential for multifunctional energy storage applications because of their outstanding electrical conductivity, superior cycling stability, and high optical transmittance. In this study, we fabricate MoCT film electrodes (referred to as MoC) on fluorine-doped tin oxide (FTO) substrates using the layer-by-layer (LbL) self-assembly technique. To improve the energy-storage performance of MoCT film electrodes, we develop a convenient electrochemical activation process to prepare in situ oxidized MoCT/MoO film electrodes (referred to as EA-MoC).
View Article and Find Full Text PDFACS Appl Mater Interfaces
January 2025
Department of Physics, National Institute of Technology Nagaland, Chumukedima, Dimapur 797103, India.
An exceedingly porous and interwoven fibrous structure was achieved in this study by interlocking titanium carbide (TiC) MXenes onto the electrospun mats using poly(vinylidene fluoride) (PVDF) as the base polymer. The fibrous membrane was further modified with the inclusion of zinc oxide (ZnO) and tungstite (WO·HO) nano/microstructures via annealing and hydrothermal approaches. Through these strategic interfaced morphological developments in novel TiC/ZnO/WO·HO heterostructures, our findings reveal enhanced wettability and charge-segregation desirable for promoting oil-water separation and photoreactivity, respectively.
View Article and Find Full Text PDFAdv Mater
January 2025
School of Chemistry and Chemical Engineering, Yangzhou University, Yangzhou, Jiangsu, 225002, P. R. China.
MXenes, have been considered as a new generation anode material in lithium-ion batteries for lower lithium-ion diffusion barriers and superior conductivity. Unfortunately, their structures are prone to aggregation and stacking, hindering further shuttle of lithium ions and electrons, resulting in lower discharge capacity. Therefore, the introduction of interlayer spacers for the preparation of MXene-based hybrids has attracted much attention.
View Article and Find Full Text PDFAdv Healthc Mater
January 2025
State Key Laboratory of Oral Diseases, National Center for Stomatology, National Clinical Research Center for Oral Diseases, Department of Orthodontics, West China Hospital of Stomatology, Sichuan University, Chengdu, 610041, China.
Immune-mediated bone regeneration driven by bone biomaterials offers a therapeutic strategy for repairing bone defects. Among 2D nanomaterials, TiCT MXenes have garnered substantial attention for their potential in tissue regeneration. This investigation concentrates on the role of MXene nanocomposites in modulating the immune microenvironment within bone defects to facilitate bone tissue restoration.
View Article and Find Full Text PDFFront Chem
December 2024
Department of Orthopaedics, The Second Affiliated Hospital of Nanchang University, Nanchang, Jiangxi, China.
Introduction: Two-dimensional (2D) MXene, recognized for its outstanding physical and chemical properties,has gained attention as a promising material in the biomedical field. However, its potential in tissue engineering applications remains underexplored. This study focuses on synthesizing SF-MXene composite electrospun fibers and evaluating their suitability for biomedical applications.
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