A universal strategy for fabrication and morphology control of polyoxometalate-based metal-organic frameworks.

Chem Commun (Camb)

Key Laboratory of Polyoxometalate Science of the Ministry of Education, College of Chemistry, Northeast Normal University, Changchun, Jilin 130024, P. R. China.

Published: February 2020

A novel method is proposed to fabricate polyoxometalate-based metal-organic frameworks (POM@MOFs) by using the ability of POMs to oxidize metals to cations. The morphology-controlled growth of POM@MOFs (NENU-n) is achieved in the absence of any modulators and an effect of polyoxoanion charge number on morphology is observed.

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Source
http://dx.doi.org/10.1039/c9cc09554cDOI Listing

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