Photo-induced glycosylation using a diaryldisulfide as an organo-Lewis photoacid catalyst.

Org Biomol Chem

Department of Applied Chemistry, Faculty of Science and Technology, Keio University, 3-14-1 Hiyoshi, Kohoku-ku, Yokohama 223-8522, Japan.

Published: February 2020

Photo-induced glycosylations of several acceptors with trichloroacetimidate donors using bis(2-naphthyl)disulfide as an organo-Lewis photoacid (LPA) catalyst proceeded effectively to give the corresponding glycosides in good to high yields. In addition, the ground and excited state absorption spectra of bis(2-naphthyl)disulfide with or without NEt suggested the Lewis acidity of bis(2-naphthyl)disulfide upon photo-irradiation.

Download full-text PDF

Source
http://dx.doi.org/10.1039/c9ob02674fDOI Listing

Publication Analysis

Top Keywords

organo-lewis photoacid
8
photo-induced glycosylation
4
glycosylation diaryldisulfide
4
diaryldisulfide organo-lewis
4
photoacid catalyst
4
catalyst photo-induced
4
photo-induced glycosylations
4
glycosylations acceptors
4
acceptors trichloroacetimidate
4
trichloroacetimidate donors
4

Similar Publications

Want AI Summaries of new PubMed Abstracts delivered to your In-box?

Enter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!