We report on copper(i)-bis(N-heterocyclic carbene)s (NHC) for quantitative stress-sensing, embedded within polyurethane networks, triggering a fluorogenic copper(i) azide alkyne cycloaddition (CuAAC) of 8-azido-2-naphtol and 3-hydroxy phenylacetylene. A completely transparent, force responsive poly(urethane) material is generated, allowing a quantification of the applied stress.
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http://dx.doi.org/10.1039/c9sm02185j | DOI Listing |
Int J Biol Macromol
December 2024
USDA Forest Service, Forest Products Laboratory, Madison, WI 53726, USA. Electronic address:
Improving flame retardancy and mechanical strength of lignin-containing polyurethane is a great challenge. In this study, lignin with favorable reactivity and dispersity was extracted from poplar using acid hydrotrope p-TsOH in EtOH. The extracted acid hydrotrope lignin (AHL) was subsequently functionalized with nitrogen and phosphorus (FHL) and reacted with isocyanate to fabricate a fire-retardant polyurethane (FHL-PU).
View Article and Find Full Text PDFACS Appl Mater Interfaces
December 2024
National Engineering Laboratory for Clean Technology of Leather Manufacture, College of Biomass Science and Engineering, Sichuan University, Chengdu 610065, P.R. China.
Advanced elastomers with outstanding strength, toughness, and reusability hold significant potential for diverse applications. Using photochemistry and mechanochemistry to develop such materials has become a very effective strategy. Here, we report that photoreversible coumarin-based mechanophores that can make force-/light-triggered cycloreversion are chemically incorporated into polyurethane elastomers to simultaneously enhance their strength and toughness.
View Article and Find Full Text PDFInt J Biol Macromol
December 2024
Guangdong Provincial Laboratory of Chemistry and Fine Chemical Engineering Jieyang Center, Jieyang 515200, PR China; Guangdong Provincial Key Laboratory of Plant Resources Biorefinery, School of Chemical Engineering and Light Industry, Guangdong University of Technology, Waihuan Xi Road 100, Guangzhou, Guangdong 510006, PR China.
Lignin, a renewable and biodegradable polymer, offers a promising alternative to petroleum-based polyols for polyurethane elastomer synthesis. However, its complex structure poses challenges, such as poor dispersibility and reactivity. This study introduces a novel one-step and solvent-free method for synthesizing lignin-containing polyurethane elastomers (SF-LPUes-ONE) with a high lignin substitution rate of at least 30 wt%.
View Article and Find Full Text PDFAdv Mater
December 2024
Engineering Research Center of Energy Storage Materials and Devices Ministry of Education, School of Chemistry, Xi'an Jiaotong University, Xi'an, 710049, China.
Hydrogels with mechanical performances similar to load-bearing tissues are in demand for in vivo applications. In this work, inspired by the self-assembly behavior of amphiphilic polymers, polyurethane-based tough hydrogels with a multiple hydrogen-bond interlocked bicontinuous phase structure through in situ water-induced microphase separation strategy are developed, in which poly(ethylene glycol)-based polyurethane (PEG-PU, hydrophilic) and poly(ε-caprolactone)-based polyurethane (PCL-PU, hydrophobic) are blended to form dry films followed by water swelling. A multiple hydrogen bonding factor, imidazolidinyl urea, is introduced into the synthesis of the two polyurethanes, and the formation of multiple hydrogen bonds between PEG-PU and PCL-PU can promote homogeneous microphase separation for the construction of bicontinuous phase structures in the hydrogel network, by which the hydrogel features break strength of 12.
View Article and Find Full Text PDFInt J Pharm
December 2024
Department of Biological, Chemical, and Pharmaceutical Sciences and Technologies (STEBICEF), University of Palermo, Via Archirafi 32, Palermo, Italy; Istituto per la Ricerca e Innovazione Biomedica (IRIB), CNR, Via Ugo La Malfa, 153, 90146, Palermo, Italy. Electronic address:
Despite advancements in cancer treatments, therapies frequently exhibit high cytotoxicity, and surgery remains the predominant method for treating most solid tumors, often with limited success in preventing post-surgical recurrence. Implantable biomaterials, designed to release drugs at a localised site in response to specific stimuli, represent a promising approach for enhancing tumour therapy. In this study, a redox-responsive glutathione extended polyurethane urea (PolyCEGS) was used to produce paclitaxel (PTX) and gold nanorods (AuNRs) loaded electrospun membranes for combined redox/near-infrared (NIR) light-responsive release chemotherapy and hyperthermic effect.
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