Detection of stress in polymers: mechanochemical activation of CuAAC click reactions in poly(urethane) networks.

Soft Matter

Macromolecular Chemistry, Division of Technical and Macromolecular Chemistry, Institute of Chemistry, Faculty of Natural Science II (Chemistry, Physics and Mathematics), Martin Luther University Halle-Wittenberg, Von-Danckelmann-Platz 4, Halle D-06120, Germany.

Published: February 2020

We report on copper(i)-bis(N-heterocyclic carbene)s (NHC) for quantitative stress-sensing, embedded within polyurethane networks, triggering a fluorogenic copper(i) azide alkyne cycloaddition (CuAAC) of 8-azido-2-naphtol and 3-hydroxy phenylacetylene. A completely transparent, force responsive poly(urethane) material is generated, allowing a quantification of the applied stress.

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http://dx.doi.org/10.1039/c9sm02185jDOI Listing

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