Structural Diversity of F-Element Monophthalocyanine Complexes.

Chemistry

Department of Chemistry, Simon Fraser University, 8888 University Drive, Burnaby, BC, V5A 1S6, Canada.

Published: January 2020

The preparation and structural characterization of a series of lanthanide and uranium(IV) phthalocyanine halide complexes were achieved by reaction of the corresponding metal halide with Li Pc. A preliminary survey of their reactivity includes ring reduction of Li(THF) [PcUCl ] with KC leading to the first structurally characterized Pc actinide complex, hydrolysis of PcDyCl(DMSO) to PcDyOH(H O) and preparation of a unique trimeric triangular Li(PcDy) (OH) (H O) cluster.

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http://dx.doi.org/10.1002/chem.201904535DOI Listing

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