Invited for this month's cover picture is the group of Professor Nobuhiro Yanai and Nobuo Kimizuka at Kyushu University. The cover picture shows visible-to-ultraviolet (vis-to-UV) triplet-triplet annihilation-based photon upconversion (TTA-UC) via triplet exciton diffusion in a chromophoric ionic liquid (IL). Chromophore moieties spontaneously form continuous arrays in non-polar nano-domains of the IL. The close arrangement of the chromophores in the IL allowed effective diffusion of triplet excitons, resulting in the vis-to-UV TTA-UC at a low excitation intensity. Read the full text of their Communication at https://doi.org/10.1002/open.201900304.
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http://www.ncbi.nlm.nih.gov/pmc/articles/PMC6946953 | PMC |
http://dx.doi.org/10.1002/open.201900358 | DOI Listing |
Adv Sci (Weinh)
January 2025
Key Laboratory for High Efficiency Energy Conversion Science and Technology of Henan Province, International Joint Research Laboratory of New Energy Materials and Devices of Henan Province, School of Physics and Electronics, Henan University, Kaifeng, 475004, P. R. China.
Multimode luminescent materials exhibit tunable photon emissions under different excitation or stimuli channels, endowing them high encoding capacity and confidentiality for anti-counterfeiting and encryption. Achieving multimode luminescence into a stable single material presents a promising but remains a challenge. Here, the downshifting/upconversion emissions, color-tuning persistent luminescence (PersL), temperature-dependent multi-color emissions, and hydrochromism are integrated into Er ions doped CsNaYbCl nanocrystals (NCs) by leveraging shallow defect levels and directed energy migration.
View Article and Find Full Text PDFAnal Chem
January 2025
Department of Life Technologies/Biotechnology, Faculty of Technology, University of Turku, Kiinamyllynkatu 10, 20520 Turku, Finland.
The anti-Stokes emission of photon upconversion nanoparticles (UCNPs) facilitates their use as labels for ultrasensitive detection in biological samples as infrared excitation does not induce autofluorescence at visible wavelengths. The detection of extremely low-abundance analytes, however, remains challenging as it is impossible to completely avoid nonspecific binding of label conjugates. To overcome this limitation, we developed a novel hybridization complex transfer technique using UCNP labels to detect short nucleic acids directly without target amplification.
View Article and Find Full Text PDFJ Phys Chem Lett
January 2025
Institute of Optoelectronic Technology, Fuzhou University, Fuzhou 350116, China.
Colloidal quantum dot (CQD) near-infrared (NIR) upconversion devices (UCDs) can directly convert low-energy NIR light into higher energy visible light without the need for additional integrated circuits, which is advantageous for NIR sensing and imaging. However, the state-of-the-art CQD NIR upconverters still face challenges, including high turn-on voltage (), low photon-to-photon (p-p) upconversion efficiency, and low current on/off ratio, primarily due to inherent limitations in the device structure and operating mechanisms. In this work, we developed a CQD NIR UCD based on a hole-only injection mechanism.
View Article and Find Full Text PDFSensors (Basel)
December 2024
Research Group for Implantable Microsystems, Faculty of Information Technology & Bionics, Pázmány Péter Catholic University, H-1083 Budapest, Hungary.
The aim of this work is to incorporate lanthanide-cored upconversion nanoparticles (UCNP) into the surface of microengineered biomedical implants to create a spatially controlled and optically releasable model drug delivery device in an integrated fashion. Our approach enables silicone-based microelectrocorticography (ECoG) implants holding platinum/iridium recording sites to serve as a stable host of UCNPs. Nanoparticles excitable in the near-infrared (lower energy) regime and emitting visible (higher energy) light are utilized in a study.
View Article and Find Full Text PDFSmall
January 2025
State Key Laboratory of Electromechanical Integrated Manufacturing of High-performance Electronic Equipment, School of Mechano-Electronic Engineering, School of Life Science and Technology, Xidian University, Xi'an, Shaanxi, 710071, China.
In this research, a novel detection method employing rare-earth upconversion nanoparticle (UCNP) as the core, coated with MnO nanosheets is designed, which formed a color and fluorescence dual-responsive UCNP composite material, MnO-modified NaYF:Yb,Tm@NaYF. By enabling both colorimetric and fluorescence methods simultaneously, this composite material allows for the detection of glucose concentration under different conditions, while exhibiting strong resistance to environmental interference, chemical stability, and accuracy. To further enhance the sensitivity of the detection method, a photonic crystals (PCs)-PDMS array where polymethyl methacrylate PCs are deposited onto a substrate composed of PDMS-glass slice with hydrophobic surfaces is developed.
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