Inspired by the freezing tolerance performances found in living creatures, an effect approach is presented to develop novel antifreezing polymeric organohydrogel actuators. Through construction of a bilayer hydrogel including a nonresponsive polyacrylamide (PAAm) layer and a pH-responsive polyacrylic acid (PAA) layer in the presence of a mixed solvent of water and glycerol, organohydrogel actuators that could produce various shape deformations at subzero temperatures have been achieved, and the actuating speed could be tuned by adjusting the temperature and the ratio between glycerol and water. Moreover, a series of application demonstrations including a weightlifting robot, artificial valve, and robotic arm have been displayed. In addition, by introducing the ionic compound KI into the glycerol-based organogel, flexible conductors that could perform stable sensing performance over a wide range of temperatures from -30°C to 60°C have been developed.
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http://dx.doi.org/10.34133/2019/2384347 | DOI Listing |
Int J Biol Macromol
March 2024
College of Chemistry and Chemical Engineering, Qingdao University, Qingdao 266071, PR China; Institute of Marine Biobased Materials, Collaborative Innovation Center of Marine Biobased Fiber and Ecological Textile Technology, State Key Laboratory of Bio-Fibers and Eco-Textiles, Qingdao University, Qingdao 266071, PR China. Electronic address:
To develop ecofriendly multifunctional gel materials for sustainable flexible electronic devices, composite organohydrogels of gellan gum (GG) and polypyrrole (PPy) with an interpenetrating network structure (IPN-GG/PPy organohydrogels) were developed first time, through fabrication of GG organohydrogels followed by in-situ oxidation polymerization of pyrrole inside. Combination of water with glycerol can not only impart environment-stability to GG hydrogels but promote the mechanics remarkably, with the compressive strength amplified by 1250 % from 0.02 to 0.
View Article and Find Full Text PDFAdv Mater
January 2024
Fibre and Polymer Technology, KTH Royal Institute of Technology, Stockholm, SE 100 44, Sweden.
A sustainable and efficient multicatalytic chemical transformation approach is devised for the development of all-biobased environmentally adaptable polymers and gels with multifunctional properties. The catalytic system, utilizing Lignin aluminum nanoparticles (AlNPs)-aluminum ions (Al ), synergistically combines multiple catalytic cycles to create robust, mechanically stable, and versatile organohydrogels. Single catalytic cycles alone fail to achieve desired results, highlighting the importance of cooperatively combining different cycles for successful outcomes.
View Article and Find Full Text PDFNat Commun
April 2023
School of Materials Science and Engineering, Nanyang Technological University, 50 Nanyang Avenue, Singapore, 639798, Singapore.
Electroadhesion provides a promising route to augment robotic functionalities with continuous, astrictive, and reversible adhesion force. However, the lack of suitable conductive/dielectric materials and processing capabilities have impeded the integration of electroadhesive modules into soft robots requiring both mechanical compliance and robustness. We present herein an iontronic adhesive based on a dynamically crosslinked gel-elastomer system, including an ionic organohydrogel as adhesive electrodes and a resilient polyurethane with high electrostatic energy density as dielectric layers.
View Article and Find Full Text PDFACS Appl Mater Interfaces
March 2023
Key Laboratory of Marine Materials and Related Technologies, Zhejiang Key Laboratory of Marine Materials and Protective Technologies, Ningbo Institute of Material Technology and Engineering, Chinese Academy of Sciences, Ningbo 315201, China.
Hydrogel actuators showing shape morphing in response to external stimuli are of significant interest for their applications in soft robots, artificial muscles, etc. However, there is still a lack of hydrogel actuators with adjustable stimulus responsiveness for on-demand driving. In this study, an organohydrogel actuator was prepared by a two-step interpenetrating method, resulting in the coexistence of poly(-isopropylacrylamide--4-(2-sulfoethyl)-1-(4-vinylbenzyl) pyridinium betaine) (p(NIPAM-SVBP)) hydrophilic networks and poly(lauryl methacrylate) (pLMA) hydrophobic networks with gradient distribution.
View Article and Find Full Text PDFAdv Mater
March 2023
Key Laboratory of Bioinspired Smart Interfacial Science and Technology of Ministry of Education, School of Chemistry, Beihang University, Beijing, 100191, P. R. China.
Current hydrogel actuators mostly suffer from weak actuation strength and low responsive speed owing to their solvent diffusion-induced volume change mechanism. Here a skeletal muscle-inspired organohydrogel actuator is reported in which solvents are confined in hydrophobic microdomains. Organohydrogel actuator is driven by compartmentalized directional network deformation instead of volume change, avoiding the limitations that originate from solvent diffusion.
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